The Crystal Structure of <I>trans</I>-Dinitratobis(trimethylenediamine)-cobalt(III) Nitrate
スポンサーリンク
概要
- 論文の詳細を見る
The crystal structure of <I>trans</I>-[Co(NO<SUB>3</SUB>)<SUB>2</SUB>(tn)<SUB>2</SUB>]NO<SUB>3</SUB> (tn: H<SUB>2</SUB>N–CH<SUB>2</SUB>–CH<SUB>2</SUB>–CH<SUB>2</SUB>–NH<SUB>2</SUB>) has been determined from three-dimensional X-ray diffraction data. The dimensions of the monoclinic unit cell are: <I>a</I>=8.62 Å, <I>b</I>=10.04 Å, <I>c</I>=9.61 Å, β=114.0°, and <I>Z</I>=2. The space group is <I>P</I>2<SUB>1</SUB>/<I>c</I>. The structure has been refined by the least-squares method to <I>R</I>=0.114. The complex ion has a slightly distorted octahedral coordination, with four N atoms of trimethylenediamine molecules at 1.990±0.009 Å and two O atoms of nitrate ions at 1.898±0.007 Å. The two six-membered cobalttrimethylenediamine rings are identical, as is required by the center of symmetry, and take the chair form. The complex ions and nitrate ions are tightly bound together by N–H···O hydrogen bonds in the layers parallel to the (100) plane, but there exists no evidence for hydrogen bonding between the layers.
- 公益社団法人 日本化学会の論文
著者
-
Kawaguchi Shinichi
Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University
-
Kawaguchi Hiroshi
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
-
Yasaki Eeki
Department of Applied Chemistry, Faculty of Engineering, Yamanashi University
-
Komiyama Yoshimichi
Department of Applied Chemistry, Faculty of Engineering, Yamanashi University
-
Oonishi Isao
Department of Applied Chemistry, Faculty of Engineering, Yamanashi University
-
Kawaguchi Hiroshi
Department of Chemistry, Faculty of Science, Osaka City University
関連論文
- Identification of sequence polymorphisms in two sulfation-related genes, PAPSS2 and SLC26A2, and an association analysis with knee osteoarthritis
- A New Experimental Correction Method for the First-Order Perturbation Approximation in the Steady Subcritical Reactor
- Transient pancytopenia associated with parvovirus infection in a healthy child
- Identification of sequence polymorphisms of the COMP (cartilage oligomeric matrix protein) gene and association study in osteoarthrosis of the knee and hip joints
- Magnetic Chromatography of Magnetic Fine Particles Suspended in a Liquid with a Steel-Bead Column under a Periodically Intermittent Magnetic Field
- Laser Ablation/Inductively Coupled Plasma Mass Spectrometry with Aerosol Density Normalization
- Optimization of Operating Conditions in Individual Airborne Particle Analysis by Inductively Coupled Plasma Mass Spectrometry
- Effect of Hydrogen Addition to the Discharge Gas in Radio-Frequency Argon Glow-Discharge Mass Spectrometry for Nonconducting Samples
- Effects of Helium Addition to Radio-Frequency Argon Glow-Discharge Mass Spectrometry
- Effect of Orifice Diameter of Torch Injector Tube in Inductively Coupled Plasma Mass Spectrometry
- OJ-534 Prognostic Value of Heart Rate Variability for All Cause and Sudden Death in Patients with Renal Failure on Hemodialysis(Kidney/Renal Circulation 3 (H) : OJ65)(Oral Presentation (Japanese))
- Design and Characterization of a Helium-Discharge Ionization Detector for Gas Chromatography
- Stereoselective Formation and Characterization of S-Bridged Dinuclear Λ- and Δ-[Co{Co(didentate-N,S)_3}(_D-pen-N,O,S)]-Type Complexes (didentate=2-Aminoethanethiolate, _L-Cysteinate, and _D-Penicillaminate (_D-pen))
- Photochemistry of Cobalt(III) Complexes. II. Cobalt(III) Complex with a Co-C-S Three-Membered Ring Prepared by Photodecarboxylation of 2,2'-Thiodiacetato Complex. Crystal Structure of (-)^_-fac-trans(NH,O)-[Co(CH_2SCH_2COO)(dien)]ClO_4
- Antineutrophil cytoplasmic antibody-positive crescentic glomerulonephritis associated with propylthiouracil therapy
- Cross-Layer Design for Low-Power Wireless Sensor Node Using Wave Clock
- Purification and Characterization of 3-Isopropylmalate Dehydrogenase from Thiobacillus thiooxidans
- A Quantitative Analysis of Rat Osteoporosis Model with a Microfocus X-ray Tube and Digital Radiography System
- Low Expression of Adhesion Molecules in a Case of Cutaneous T-cell Lymphoma
- Neurologic Level Diagnosis of Cervical Stenotic Myelopathy
- A 58-μW Single-Chip Sensor Node Processor with Communication Centric Design
- A power-variation model for sensor node and the impact against life time of wireless sensor networks
- A 50% Power Reduction in H.264/AVC HDTV Video Decoder LSI by Dynamic Voltage Scaling in Elastic Pipeline(VLSI Architecture,VLSI Design and CAD Algorithms)
- A Case of Polypoid Clear Cell Acanthoma on the Scrotum
- Adult Onset of Inflammatory Linear Verrucous Epidermal Nevus
- Vertebral hemangioma compressing the thoracic spinal cord : application of computer-aided navigation and intraoperative spinal sonography for surgery through anterior and posterior approaches
- Revision cervical spine surgery using transarticular or pedicle screws under a computer-assisted image-guidance system
- Can Laminoplasty Maintain the Cervical Alignment Even When the C2 Lamina Is Contained?
- Postoperative Expansion of Intramedullary High-Intensity Areas on T2-Weighted Magnetic Resonance Imaging After Cervical Laminoplasty
- Retroodontoid pseudotumor resected by a high cervical lateral approach in a rheumatoid arthritis patient : a case report
- Cervical myelopathy in an adult due to atlantoaxial subluxation associated with Down syndrome : a case study
- Image-guided surgery for cervical disorders in rheumatoid arthritis
- Association of Bone Metabolism Regulatory Factor Gene Polymorphisms With Susceptibility to Ossification of the Posterior Longitudinal Ligament of the Spine and Its Severity
- Computer-assisted anterior spinal surgery for a case of recurrent giant cell tumor
- Long-Term Results of Operative Treatment for Cervical Spondylotic Myelopathy in Patients With Athetoid Cerebral Palsy : An Over 10-Year Follow-Up Study
- Long-Term Results of Double-Door Laminoplasty for Cervical Stenotic Myelopathy
- Determination of Ultratrace Indium in Water Sample by Electrothermal Atomic Absorption Spectrometry after Preconcentration with Solvent Extraction and Back Extraction
- Determination of Ultratrace Gallium in River Water by Electrothermal Atomic Absorption Spectrometry after Preconcentration with Solvent Extraction and Back Extraction
- Diet and lifestyle associated with increased bone mineral density : cross-sectional study of Japanese elderly women at an osteoporosis outpatient clinic
- Risk factors for knee osteoarthritis in Japanese men : a case-control study
- Overproduction and Substrate Specificity of 3-Isopropylmalate Dehydrogenase from Thiobacillus ferrooxidans
- The Incomplete Cubane Complexes Having Co_3O_4 or Mo_3S_4 Core with the N-N-O Type Tridentates; L-histidinato and Ethylenediamine-N-acetato
- Mutation in Aging Suppressor Gene, Klotho, Causes Decreases in Bone Formation and Resorption in Mice(Advances in Connective Tissue Research in Bone and Joint)
- A 0.3-V operating, Vth-variation-tolerant SRAM under DVS environment for memory-rich SoC in 90-nm technology era and beyond
- Exposure of macrophage-like cells to titanium particles does not affect bone resorption, but inhibits bone formation
- Curative Effect of Combined Treatment With Alendronate and 1α-Hydroxyvitamin D_3 on Bone Loss by Ovariectomy in Aged Rats
- Synthesis and X-Ray Structural Study of Magnesium (1, 3-Propanediaminetetraacetato)nickelate(II) Octahydrate, Mg[Ni(1, 3-pdta)]・8H_2O. Structural Parameters and Strain Analysis of [M(1, 3-pdta)]^ Complexes in Relation to Their Octahedral Distortion
- Preparation and Crystal Structure of the trans(O^5) Isomer of Magnesium(ethylenediamine-N,N,N'-triacetato-N'-3-propionato)cuprate(II)Octahydrate, Mg[Cu(ed3ap)]・8H_2O. Stereochemistry of Octahedral Cu(II)-EDTA-Type Complexes in Relation to the Structure of
- Synthesis and Characterization of Hexadentate Cobalt(III) Complexes with New edta-Type Ligands Part 5. Structure and Absolute Configuration of the trans(O_5)(-)_-Isomer of Lithium (Ethylenediamine-N, N, N'-triacetato-N'-3-propionato)cobaltate(III)Mon
- A polymorphic variant at the Werner helicase(WRN)gene is associated with bone density, but not spondylosis, in postmenopausal women
- Prevalence of knee osteoarthritis, lumbar spondylosis, and osteoporosis in Japanese men and women : the research on osteoarthritis/osteoporosis against disability study
- Satisfaction and the Correlative Outcomes in Cervical Laminoplasty
- Association of low dietary vitamin K intake with radiographic knee osteoarthritis in the Japanese elderly population : dietary survey in a population-based cohort of the ROAD study
- Determination of Ultratrace Beryllium in Natural Water by Electrothermal Atomic Absorption Spectrometry after Preconcentration with One-Drop Solvent
- Regulatory Region of Expression of Thiobacillus ferrooxidans leuB Gene in Escherichia coli
- Impact of knee and low back pain on health-related quality of life in Japanese women : the Research on Osteoarthritis Against Disability (ROAD)
- Stereoselective Formation of[Cr(edda or eddp)(N-N)-Type Complexes with 1, 10-Phenanthroline(edda=ethylenediamine-N, N'-diacetate;eddp=ethylenediamine-N, N'-dipropionate)
- Identification of oxytetracycline as a chondrogenic compound using a cell-based screening system
- Normal and threshold values of radiographic parameters for knee osteoarthritis using a computer-assisted measuring system (KOACAD) : the ROAD study
- Optically Active Cobalt(III) Complexes Containing Partial Cubane Co_3O_4 Core: Syntheses and Structures of the Isomers of [Co_3(L)_3(μ-OH)_3(μ_3-O)]Cl (L = Ethylenediamine-N-acetate)
- Tetranuclear Cobalt(III) Complex Having the Cubane Co_4O_4 Core: Synthesis and Structural Analysis of the Complex Containing (2-Pyridylmethyl)glycine
- Radiation-Induced Astrocytoma With Rapid Malignant Transformation : Case Report
- Solid-Liquid Extraction with an Ammoniacal EDTA Solution for the Separation of Traces of Copper from Aluminum
- Use of Surfactant Aggregates Formed on Alumina for the Preparation of Chelating Sorbents
- Trinuclear Cobalt(III) Complex Having Partial Cubane Co_3O_4 Core : Synthesis and Structural Analysis of the Complex Containing Bis(2-pyridylmethyl)amine
- Metal Complexes of Peptides. VI. Di-μ-hydroxo-Dicobalt(III) Complexes Containing Peptides
- Trinuclear Cobalt(III) Complexes Containing Partial Cubane Co_3O_4 Core. Synthesis and Structure of [Co_3(L)_3(μ-OH)_3(μ_3-O)]Cl (L=ethylenediamine-N-acetate)
- Photochemistry of Cobalt(III) Complexes. I. Optically Active Cobalt(II) Complexes Containing Co-C Bond Prepared by Photodecarboxylation of Amino Carboxylato Complexes
- Stereospecific Deuteration of Chelated 2,2'-Thiodiacetate(tda)in[Co(dien)(tda)]+(dien=diethylenetriamine)Observed in the Acidic D2O Solutions
- Double Sulfur Trans Influence in the Dithiolato Complex: trans(S)-[Co(aet)_2(en)]ClO_4(aet=2-Aminoethanetiolate)
- Capacity of endogenous sex steroids to predict bone loss in Japanese men : 10-year follow-up of the Taiji Cohort Study
- Plasma brain natriuretic peptide concentrations in patients with Kawasaki disease
- A case of congenital nasal pyriform aperture stenosis
- Determination of Trace Molybdenum in Water Samples by Electrothermal Atomic Absorption Spectrometry after Preconcentration with Miniaturized Coprecipitation
- Matrix Precipitation for the Analysis of High-Purity Tin Metal by Electrothermal Atomic Absorption Spectrometry
- Coprecipitation with Microgram Quantities of Indium Hydroxide for the Determination of Trace Heavy Metals in Rain Water
- Intraoperative ultrasonographic evaluation of the posterior decompression by laminoplasty in patients with cervical ossification of the posterior longitudinal ligament
- Separation of Traces of Copper(II) from an Aluminum Matrix with a Thermally Reversible Polymer
- Osteoclastic bone resorption through receptor tyrosine kinase and extracellular signal-regulated kinase signaling in mature osteoclasts
- A Low-Power Multi Resolution Spectrum Sensing Architecture for a Wireless Sensor Network with Cognitive Radio
- Biochemical markers of bone turnover as predictors of osteoporosis and osteoporotic fractures in men and women : 10-year follow-up of the Taiji cohort
- Reactions of trans- and cis-dichlorobis(benzonitrile)platinum(II) with acetylacetonate and benzoylacetonate carbanions. Formation of N-acetyl .BETA.-ketoamine complexes by the acetyl group migration.
- The syntheses and properties of bis(3-hydroxy-2-methyl-4-pyronato) complexes of bivalent metal ions.
- Some Metal Complexes Containing Ethyl Acetoacetate or Ethyl Malonate as a Neutral Ligand
- Organonickel(II) complexes containing carbon-bonded heterocycles as a ligand.
- cis-Dioxovanadium(V) and mixed-valence divanadium(IV,V) complexes containing .BETA.-diketonate and heterocyclic nitrogen-base ligands.
- Some Mixed-Ligand Manganese(III) Complexes Produced by the Reactions of Tris(acetylacetonato)manganese(III) with Hydrogen Halides in Organic Solvents
- Some palladium(II) complexes containing both the O-unidentate .BETA.-diketonato and 2-,3-, or 4-pyridyl ligands. Dynamic behaviors of trans-(Pd(.BETA.-dik-O)(C5H3(6-Cl)N-C2)(PEt3)2) in solution.
- Trinuclear Intermediates Isolated in the Reactions of Bis(acetylacetonato)-nickel(II) with Dry Hydrogen Bromide
- The Reaction of Bis(acetylacetonato)cobalt(II) with Bromine in Dichloromethane
- Trimethylenediamine complexes. VIII. Some cis-trans isomeric pairs of the bis(trimethylenediamine)chromium(III) complexes.
- Reactions of Tris(acetylacetonato)manganese(III) and Bis(acetylacetonato)-manganese(II) with Ethylenediamine and Other Primary Amines
- Kinetic and equilibrium studies on substitution reactions of the chlorobis(.BETA.-diketonato)manganese(III) complexes with other .BETA.-diketones.
- Trimethylenediamine Complexes. III. cis-trans Isomeric Pairs of Diazido- and Dicyano-bis(trimethylenediamine)cobalt(III) Complexes
- The Crystal Structure of trans-Dinitratobis(trimethylenediamine)-cobalt(III) Nitrate
- X-ray structures of (-)589-bis(isothiocyanato)bis(1,3-propanediamine)-chromium(III) bis(.MU.-(+)-tartrato(4-))bis(antimonate(III)) dihydrate and its cobalt(III) analogue.
- Trimethylenediamine Complexes. II. Some cis-trans Isomeric Pairs of Diacidobis(trimethylenediamine)cobalt(III) Complexes
- C,O-chelates of the trifluoroacetylacetonate dianion with palladium(II). Molecular structure of (Pd(tfac(2-)-C,O)(PPh3)(2,6-Me2-py))
- Kinetics and mechanism of the reactions of bis(acetylacetonato)-palladium(II) with alkylamines.
- Palladim(II) complexes derived from the reactions of bis(3-hydroxy-2-methyl-4-pyronato)palladium(II) with several nitrogen bases.