Reactions of Tris(acetylacetonato)manganese(III) and Bis(acetylacetonato)-manganese(II) with Ethylenediamine and Other Primary Amines

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概要

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• Tris(acetylacetonato)manganese(III) reacts with ethylenediamine (L<SUB>2</SUB>) and other primary amines (L) in organic solvents at room temperature producing Mn(acac)<SUB>2</SUB>L<SUB>2</SUB>. The same Mn(II) complexes were also prepared quantitatively by reactions of Mn(acac)<SUB>2</SUB>(H<SUB>2</SUB>O)<SUB>2</SUB> with amines. Besides the usual hexa-coordinate monomeric complex, allylamine gave a dimeric compound [Mn(acac)<SUB>2</SUB>(CH<SUB>2</SUB>=CHCH<SUB>2</SUB>NH<SUB>2</SUB>)]<SUB>2</SUB>, which is the first example of the binuclear manganese(II) complex of acetylacetone. The stoichiometry of the redox reaction between Mn(acac)<SUB>3</SUB> and ethylenediamine was established and discussed in connection with the initiation mechanism of vinyl polymerization.

• 公益社団法人 日本化学会の論文

著者

• Nakamura Yukio

  Department Of Biotechnology Faculty Of Agriculture Gifu University

• Kawaguchi Shinichi

  Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University

• Nishikawa Yoshinori

  Department of Chemistry, Faculty of Science, Osaka City University

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