X-ray structures of (-)589-bis(isothiocyanato)bis(1,3-propanediamine)-chromium(III) bis(.MU.-(+)-tartrato(4-))bis(antimonate(III)) dihydrate and its cobalt(III) analogue.

スポンサーリンク

概要

• 論文の詳細を見る

• The crystal structures of (−)<SUB>589</SUB>-[Cr(NCS)<SUB>2</SUB>(tn)<SUB>2</SUB>]1/2[Sb<SUB>2</SUB>(+)-tart<SUB>2</SUB>]·2H<SUB>2</SUB>O (<B>1</B>) and (−)<SUB>589</SUB>-[Co(NCS)<SUB>2</SUB>(tn)<SUB>2</SUB>]1/2-[Sb<SUB>2</SUB>(+)-tart<SUB>2</SUB>]·2H<SUB>2</SUB>O (<B>2</B>) have been determined from the X-ray diffraction data. The structures were solved by the Patterson-Fourier method and refined by the least-squares method to <I>R</I>=0.043 (<B>1</B>) and 0.070 (<B>2</B>) for 2659 and 1826 reflections respectively. The two crystals are isomorphous with each other. The complex cations in <B>1</B> and <B>2</B> have a similar geometry. Their absolute configuration is <I>Λ</I>, and agrees with that assigned from the CD spectra in comparison with those in the first d-d band region of bis(ethylenediamine)cobalt(III) complexes. The six-membered chelate rings are of chair conformation. The chairs are flattened more than expected from the conformational analysis.

• 公益社団法人 日本化学会の論文

著者

• Kawaguchi Shinichi

  Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Kawaguchi Hiroshi

  Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University

• Nakano Mamoru

  Department of Chemistry, Faculty of Science, Osaka City University

関連論文

• A transformation formula for Appell's hypergeometric function $F_1$ and common limits of triple sequences by mean iterations
• Identification of sequence polymorphisms in two sulfation-related genes, PAPSS2 and SLC26A2, and an association analysis with knee osteoarthritis
• A New Experimental Correction Method for the First-Order Perturbation Approximation in the Steady Subcritical Reactor
• Transient pancytopenia associated with parvovirus infection in a healthy child
• Identification of sequence polymorphisms of the COMP (cartilage oligomeric matrix protein) gene and association study in osteoarthrosis of the knee and hip joints
• Magnetic Chromatography of Magnetic Fine Particles Suspended in a Liquid with a Steel-Bead Column under a Periodically Intermittent Magnetic Field
• Laser Ablation/Inductively Coupled Plasma Mass Spectrometry with Aerosol Density Normalization
• Optimization of Operating Conditions in Individual Airborne Particle Analysis by Inductively Coupled Plasma Mass Spectrometry
• Effect of Hydrogen Addition to the Discharge Gas in Radio-Frequency Argon Glow-Discharge Mass Spectrometry for Nonconducting Samples
• Effects of Helium Addition to Radio-Frequency Argon Glow-Discharge Mass Spectrometry
• Effect of Orifice Diameter of Torch Injector Tube in Inductively Coupled Plasma Mass Spectrometry
• Activated peripheral blood mononuclear cells detected in lupus patients using cDNA coding for proliferating cell nuclear antigen
• OJ-534 Prognostic Value of Heart Rate Variability for All Cause and Sudden Death in Patients with Renal Failure on Hemodialysis(Kidney/Renal Circulation 3 (H) : OJ65)(Oral Presentation (Japanese))
• Design and Characterization of a Helium-Discharge Ionization Detector for Gas Chromatography
• Stereoselective Formation and Characterization of S-Bridged Dinuclear Λ- and Δ-[Co{Co(didentate-N,S)_3}(_D-pen-N,O,S)]-Type Complexes (didentate=2-Aminoethanethiolate, _L-Cysteinate, and _D-Penicillaminate (_D-pen))
• Photochemistry of Cobalt(III) Complexes. II. Cobalt(III) Complex with a Co-C-S Three-Membered Ring Prepared by Photodecarboxylation of 2,2'-Thiodiacetato Complex. Crystal Structure of (-)^_-fac-trans(NH,O)-[Co(CH_2SCH_2COO)(dien)]ClO_4
• Antineutrophil cytoplasmic antibody-positive crescentic glomerulonephritis associated with propylthiouracil therapy
• Cross-Layer Design for Low-Power Wireless Sensor Node Using Wave Clock
• Coexpression of hepatocyte growth factor and its receptor c-Met correlates with high MIB-1 proliferative index in malignant fibrous histiocytoma
• Neural fibrolipoma of the superficial peroneal nerve in the ankle: A case report with immunohistochemical analysis
• Purification and Characterization of 3-Isopropylmalate Dehydrogenase from Thiobacillus thiooxidans
• A Quantitative Analysis of Rat Osteoporosis Model with a Microfocus X-ray Tube and Digital Radiography System
• Low Expression of Adhesion Molecules in a Case of Cutaneous T-cell Lymphoma
• Neurologic Level Diagnosis of Cervical Stenotic Myelopathy
• A 58-μW Single-Chip Sensor Node Processor with Communication Centric Design
• A power-variation model for sensor node and the impact against life time of wireless sensor networks
• A 50% Power Reduction in H.264/AVC HDTV Video Decoder LSI by Dynamic Voltage Scaling in Elastic Pipeline(VLSI Architecture,VLSI Design and CAD Algorithms)
• A Case of Polypoid Clear Cell Acanthoma on the Scrotum
• Adult Onset of Inflammatory Linear Verrucous Epidermal Nevus
• Vertebral hemangioma compressing the thoracic spinal cord : application of computer-aided navigation and intraoperative spinal sonography for surgery through anterior and posterior approaches
• Revision cervical spine surgery using transarticular or pedicle screws under a computer-assisted image-guidance system
• Can Laminoplasty Maintain the Cervical Alignment Even When the C2 Lamina Is Contained?
• Postoperative Expansion of Intramedullary High-Intensity Areas on T2-Weighted Magnetic Resonance Imaging After Cervical Laminoplasty
• Retroodontoid pseudotumor resected by a high cervical lateral approach in a rheumatoid arthritis patient : a case report
• Cervical myelopathy in an adult due to atlantoaxial subluxation associated with Down syndrome : a case study
• Image-guided surgery for cervical disorders in rheumatoid arthritis
• Association of Bone Metabolism Regulatory Factor Gene Polymorphisms With Susceptibility to Ossification of the Posterior Longitudinal Ligament of the Spine and Its Severity
• Computer-assisted anterior spinal surgery for a case of recurrent giant cell tumor
• Long-Term Results of Operative Treatment for Cervical Spondylotic Myelopathy in Patients With Athetoid Cerebral Palsy : An Over 10-Year Follow-Up Study
• The Formation of Monomethyl Carbonato-bridged Dinuclear Nickel(II)Complexes by an Efficient CO_2 Uptake in Methanol Containing Urea Derivatives
• Linear Trinuclear Copper(II) Complexes Bridged by Oximato and Azido or Hydroxo Groups
• Synthesis, Structures, and Magnetic Properties ofDinuclear Nickel(II) Complexes ContainingN,N,N',N'-Tetrakis[(1-methyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane and a Thiocyanate Ion
• Kinetic Analysis of Malignant Fibrous Histiocytoma Cells Treated with Anticancer Agents In Vivo
• Early detection of a deep-seated synovial sarcoma by magnetic resonance imaging
• Bizarre Parosteal Osteochondromatous Proliferation(BPOP) of Bone : Report of Two Cases Treated with EHDP
• Kinetic Analysis of Tumor Cells in Bone and Soft Tissue Sarcomas
• Establishment and characterization of cell line TNMY1 derived from human malignant fibrous histiocytoma
• A Case of Lung Cancer with Chest Wall Invasion Showed a Pathologically Complete Response to Preoperative Thermo-chemo-radiotherapy
• Hydrogen Protection from Methanol or Methane by the Use of Thermally Generated Holes in TiO2
• Characterization of Various TiO2 Powders Used for Complete Decomposition of Organic Wastes by Means of Thermally Excited Holes at High Temperatures
• Preparation, Characterization, and X-Ray Crystal Structures of μ-2,6-Dimethylpyridine-α,α'-diyl Iridium(III)-Rhodium(III) Complexes and the Structure of [Rh_2Cl_4(μ-CH_2-py-CH_2)(PPh_3)_2] (CH_2-py-CH_2 = 2,6-Dimethylpyridine-α,α'-diyl) Reinvestigated
• A variant of Jacobi type formula for Picard curves
• Intersection theory for twisted cohomologies and twisted Riemann's period relations I : To the memory of Professor Michitake Kita
• Quadratic relations for confluent hypergeometric functions
• Braid group and a confluent hypergeometric function
• Certain reflection groups acting on symmetric domains of type IV
• Complete Decomposition of Benzene, Toluene, and Particulate Matter Contained in the Exhaust of Diesel Engines by Means of Thermally Excited Holes in Titanium Dioxide at High Temperatures
• THE PERFECTNESS OF THE INTERSECTION PAIRINGS FOR TWISTED COHOMOLOGY AND HOMOLOGY GROUPS WITH RESPECT TO RATIONAL 1-FORMS
• The crystal structure of (+)350-diammine-N,N,N'-trimethylethylenediamineplatinum(II) di-.MU.-(+)-tartrato(4-)bis(antimonate(III) monohydrate.
• Preparation, resolution, and absorption and circular dichroism spectra of (Co(en)n{NH2CH2CH2P(CH3)2}3-n)3+ and the related complexes, and the absolute configuration of (+)589-fac-(Co{NH2CH2CH2P(CH3)2}3)3+ determined by X-ray analysis.
• The preparation of pyridinium .MU.-oxo-bis(nitrilotriacetatodioxomolybdate(VI)) and pyridinium di-.MU.-oxo-bis(nitrilotriacetatooxomolybdate(V)) monohydrate and the X-ray structure of the molybdenum(VI) complex.
• The preparation and X-ray structures of di-.MU.-sulfido- and .MU.-oxo-.MU.-sulfido-bis(tris(isothiocyanato)oxomolybdate(V)) ions.
• The stereochemistry of the six geometrical isomers of the bis(ethylenediamine-N-acetato)cobalt(III) ion, (Co(edma)2)+.
• The Structure of the trans-Dichlorobistrimethylenediaminecobalt(III) Ion, trans-[CoCl2tn2]+
• タイトル無し
• Reactions of trans- and cis-dichlorobis(benzonitrile)platinum(II) with acetylacetonate and benzoylacetonate carbanions. Formation of N-acetyl .BETA.-ketoamine complexes by the acetyl group migration.
• Bridges in polynuclear complexes. II. An X-ray investigation of the coordination of silver ion to the .MU.-peroxo bridge of a dinuclear Cobalt(III) complex.
• The crystal and molecular structure of the aquabis(cyclo-L-histidyl-L-histidylato)dicopper(II) perchlorate hydrate [H2O Cu2(C12H13N6O2)2](ClO4)2 3.5H2O.
• The syntheses and properties of bis(3-hydroxy-2-methyl-4-pyronato) complexes of bivalent metal ions.
• Some Metal Complexes Containing Ethyl Acetoacetate or Ethyl Malonate as a Neutral Ligand
• Organonickel(II) complexes containing carbon-bonded heterocycles as a ligand.
• cis-Dioxovanadium(V) and mixed-valence divanadium(IV,V) complexes containing .BETA.-diketonate and heterocyclic nitrogen-base ligands.
• Some Mixed-Ligand Manganese(III) Complexes Produced by the Reactions of Tris(acetylacetonato)manganese(III) with Hydrogen Halides in Organic Solvents
• Some palladium(II) complexes containing both the O-unidentate .BETA.-diketonato and 2-,3-, or 4-pyridyl ligands. Dynamic behaviors of trans-(Pd(.BETA.-dik-O)(C5H3(6-Cl)N-C2)(PEt3)2) in solution.
• Trinuclear Intermediates Isolated in the Reactions of Bis(acetylacetonato)-nickel(II) with Dry Hydrogen Bromide
• The Reaction of Bis(acetylacetonato)cobalt(II) with Bromine in Dichloromethane
• Trimethylenediamine complexes. VIII. Some cis-trans isomeric pairs of the bis(trimethylenediamine)chromium(III) complexes.
• The crystal structures of monoclinic and triclinic forms of bis[(R)-1,2-propanediame]platinum(II) chloride dihydrate.
• Reactions of Tris(acetylacetonato)manganese(III) and Bis(acetylacetonato)-manganese(II) with Ethylenediamine and Other Primary Amines
• Kinetic and equilibrium studies on substitution reactions of the chlorobis(.BETA.-diketonato)manganese(III) complexes with other .BETA.-diketones.
• Trimethylenediamine Complexes. III. cis-trans Isomeric Pairs of Diazido- and Dicyano-bis(trimethylenediamine)cobalt(III) Complexes
• The Crystal Structure of trans-Dinitratobis(trimethylenediamine)-cobalt(III) Nitrate
• X-ray structures of (-)589-bis(isothiocyanato)bis(1,3-propanediamine)-chromium(III) bis(.MU.-(+)-tartrato(4-))bis(antimonate(III)) dihydrate and its cobalt(III) analogue.
• X-ray structures of Cu(II) chelates of cis-1,3-cyclohexanediamine.
• Trimethylenediamine Complexes. II. Some cis-trans Isomeric Pairs of Diacidobis(trimethylenediamine)cobalt(III) Complexes
• The absolute configuration and circular dichroism of the (-)260-[Pt(NH3)2(N1-Me-(S)-pn)]2+.
• The crystal structure and absolute configuration of (-)589-bis(2,4-pentanedionato)(1,3-propanediamine)chromium(III) iodide monohydrate.
• The Crystal Structure of (−)589-Dinitrobis(ethylenediamine)cobalt(III) (+)589-Bis(malonato)ethylenediaminecobaltate(III)
• The Crystal Structure of (+)589-Dicyanobis(ethylenediamine)cobalt(III) Chloride Monohydrate
• Synthesis and X-ray structure of triethylenetetraminepalladium(II) complex.
• X-Ray Study of the Compound Obtained by the Reaction of Nδ-Salicylidene-L-ornithine and Palladium(II) acetate. The Crystal Structure of (Nα-Salicylidene-D-ornithinato) (Nα-Salicylidene-L-ornithinato)di
• C,O-chelates of the trifluoroacetylacetonate dianion with palladium(II). Molecular structure of (Pd(tfac(2-)-C,O)(PPh3)(2,6-Me2-py))
• Kinetics and mechanism of the reactions of bis(acetylacetonato)-palladium(II) with alkylamines.
• The crystal structures of bis(cis-1,3-diaminocyclohexane)palladium(II) chloride and its platinum(II) analogue.
• The Crystal Structure of (−)589-Dinitrobis(ethylenediamine)cobalt(III) (+)589-Bis(malonato)ethylenediaminecobaltate(III)
• Palladim(II) complexes derived from the reactions of bis(3-hydroxy-2-methyl-4-pyronato)palladium(II) with several nitrogen bases.
• X-ray structure and magnetism of .MU.-bromo-.MU.-pyrazolatobis(diethylenetriaminecopper(II)) perchlorate monohydrate.
• The Absolute Configuration of the (−)589-Oxalatobis(ethylenediamine)-cobalt(III) Ion as Determined by X-Ray Structure Analysis
• The crystal structure of (+)350-(R)-propylenediamine-N,N'-dimethylethylenediamineplatinum(II) di-.MU.-(+)-tartrato(4-)-bis(antimonate(III) dihydrate.
• Electron Spectroscopy of Ultrathin Cycloalkane Films on Graphite (0001): Molecular Orbitals, Conformation, and Orientation

もっと見る 閉じる

スポンサーリンク