The crystal structures of bis(cis-1,3-diaminocyclohexane)palladium(II) chloride and its platinum(II) analogue.

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概要

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• The structure of bis(<I>cis</I>-1,3-diaminocyclohexane) palladium(II) chloride has been determined from X-ray diffraction data collected by the counter method. The crystal is orthorhombic with space group Pnnm, <I>a</I>=17.728(5), <I>b</I>=6.418(4), <I>c</I>=6.914(2) Å, and <I>Z</I>=2. The crystal structure has been determined by Patterson and Fourier techniques and refined by a least-squares method to <I>R</I>=0.026 for 1151 independent reflections for which <I>F</I><SUB>o</SUB><SUP>2</SUP>>3σ(<I>F</I><SUB>o</SUB><SUP>2</SUP>). The Pd atom has a planar coordination of 4N atoms and the complex cation has a crystallographically imposed C<SUB>2h</SUB> symmetry, the two <I>cis</I>-1,3-diaminocyclohexane ligands being related to each other by a two fold axis. The six-membered chelate ring (<U>Remark: Graphics omitted.</U>) is of the envelope conformation. The structural features of the ligating <I>cis</I>-1,3-diaminocyclohexane have been described. The crystal of bis(<I>cis</I>-1,3-diaminocyclohexane)platinum(II) (orthorhombic, <I>a</I>=17.727(8), <I>b</I>=6.371(3), <I>c</I>=6.965(2) Å) was found to be isomorphous with that of the palladium analogue.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Kidani Yoshinori

  Faculty Of Pharmaceutical Sciences Nagoya City University

• Kuroya Hisao

  Department of Chemistry, Okayama University of Science

• Saito Reiko

  Aichi Junior College of Nursing

• Kamisawa Keiko

  Department of Chemistry, Faculty of Science, Osaka City University

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