Studies of Bivalent Metal Complexes of 2-Acetylpyridine
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概要
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Bivalent metal complexes of 2-acetylpyridine (abbreviated as 2AP), M(2AP)<SUB>2</SUB>X<SUB>2</SUB>, M being copper, nickel, cobalt, and zinc ions and X being chloride, bromide, and iodide ions, were synthesized in ethanol solutions. The far-infrared analyses were discussed with reference to their structures, which were determined by means of the magnetic moments and the diffuse reflectance spectra. Except for Co(2AP)<SUB>2</SUB>Cl<SUB>2</SUB> and Co(2AP)<SUB>2</SUB>I<SUB>2</SUB>, an octahedral structure was suggested for the M(2AP)<SUB>2</SUB>X<SUB>2</SUB> complexes. A tetrahedral structure was assigned to Co(2AP)<SUB>2</SUB>Cl<SUB>2</SUB> and Co(2AP)<SUB>2</SUB>I<SUB>2</SUB> on the basis of their magnetic moments of 4.55 and 4.25 B.M. respectively and the diffuse reflectance spectra. The stretching vibrations of metal-nitrogen, metal-oxygen, and metal-halogen have been discussed.
- 公益社団法人 日本化学会の論文
著者
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Noji Masahide
Faculty Of Pharmaceutical Sciences Nagoya City University
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Kidani Yoshinori
Faculty Of Pharmaceutical Sciences Nagoya City University
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Koike Hisashi
Faculty of Pharmaceutical Sciences, Nagoya City University
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