Studies of Bivalent Metal Chelates of 2-Aminomethylpyridine
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概要
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Bivalent metal chelates of 2-aminomethylpyridine (abbreviated as 2AMP), M(2AMP)<SUB>2</SUB>X<SUB>2</SUB> (M=Cu, Ni, Co, and Zn ion; X=Cl<SUP>−</SUP>, Br<SUP>−</SUP>, I<SUP>−</SUP>), were synthesized in ethanol. The magnetic moments and the diffuse reflectance spectra were measured. The Cu(2AMP)<SUB>2</SUB>X<SUB>2</SUB> complexes (X=Cl<SUP>−</SUP> and Br<SUP>−</SUP>) were considered to have a monomeric distorted octahedral structure. The Ni(2AMP)<SUB>2</SUB>X<SUB>2</SUB> complexes (X=Cl<SUP>−</SUP>, Br<SUP>−</SUP>, I<SUP>−</SUP>) were also suggested to have an octahedral structure. However, for Co(2AMP)<SUB>2</SUB>Br<SUB>2</SUB> and Co(2AMP)<SUB>2</SUB>I<SUB>2</SUB> a tetrahedral and a square planar structure were proposed on the basis of their magnetic moments of 4.20 and 2.78 B.M. respectively. The infrared spectra of the chelates were analysed in relation to their structures; a good relationship was found between the structures and the far-infrared spectra.
- 公益社団法人 日本化学会の論文
著者
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Noji Masahide
Faculty Of Pharmaceutical Sciences Nagoya City University
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Kidani Yoshinori
Faculty Of Pharmaceutical Sciences Nagoya City University
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Koike Hisashi
Faculty of Pharmaceutical Sciences, Nagoya City University
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