The crystal structure of (+)350-diammine-N,N,N'-trimethylethylenediamineplatinum(II) di-.MU.-(+)-tartrato(4-)bis(antimonate(III) monohydrate.

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概要

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• X-Ray structure analysis of the title compound has revealed that the asymmetric secondary nitrogen center in the complex cation has the <I>S</I> absolute configuration. The crystals are orthorhombic, with the space group P2<SUB>1</SUB>2<SUB>1</SUB>2<SUB>1</SUB>and with <I>Z</I>=4 in a unit cell with dimensions of: <I>a</I>=18.783(6), <I>b</I>=14.138(4), and <I>c</I>=8.473(2)Å. The crystal structure has been determined from three-dimensional diffractometer data and refined by the least-squares method to <I>R</I> of 0.030 for 1971 independent reflections with <I>I</I>>3σ(<I>I</I>). The Pt atom has a square-planar coordination by four N atoms, and the methyl group bonded to the secondary nitrogen is equatorial with respect to the chelate ring. Each complex cation is surrounded octahedrally by six di-μ-(+)-tartrato(4-)-bis(antimonate(III)) anions.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Kuroya Hisao

  Department of Chemistry, Okayama University of Science

• Yokoho Keiji

  Department of Chemistry, Faculty of Science, Osaka City University

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