The crystal structure of (+)350-(R)-propylenediamine-N,N'-dimethylethylenediamineplatinum(II) di-.MU.-(+)-tartrato(4-)-bis(antimonate(III) dihydrate.

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概要

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• The crystal of the title compound is monoclinic, with <I>a</I>=9.415(3), <I>b</I>=15.767(7), <I>c</I>=8.786(3) Å, β=94.25(4)°, the space group of P2<SUB>1</SUB> and <I>Z</I>=2. The structure was determined from the counter intensity data by heavy-atom techniques and was refined by the block-diagonal least-squares calculations to <I>R</I> 0.050 for 2604 non-zero reflections. The Pt atom has a square-planar coordination by 4N atoms, the secondary N atoms of which are of the <I>S</I> absolute configuration.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Kuroya Hisao

  Department of Chemistry, Okayama University of Science

• Sakuma Masao

  Department of Chemistry, Faculty of Science, Osaka City University

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