X-ray structure and magnetism of .MU.-bromo-.MU.-pyrazolatobis(diethylenetriaminecopper(II)) perchlorate monohydrate.

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概要

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• The structure of the title compound has been determined by an X-ray method. The dinuclear complex is composed of two Cu(dien) units which are bridged by pyrazolate and Br<SUP>−</SUP> anions. The geometry around each copper(II) may be described as a square pyramid. The antiferromagnetic interaction within the dinuclear complex has been observed (<I>J</I>=−14 cm<SUP>−1</SUP>, <I>H</I>=−2<I>JS</I><SUB>1</SUB>·<I>S</I><SUB>2</SUB>).

• 公益社団法人 日本化学会の論文

著者

• NAKAO Yasuo

  Chemical Laboratory, Faculty of Education Okayama University

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Mori Wasuke

  Institute of Chemistry, College of General Education, Osaka University

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