The preparation and X-ray structures of di-.MU.-sulfido- and .MU.-oxo-.MU.-sulfido-bis(tris(isothiocyanato)oxomolybdate(V)) ions.

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概要

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• The crystal structures of (pyH)<SUB>4</SUB>[Mo<SUB>2</SUB>O<SUB>2</SUB>S<SUB>2</SUB>(NCS)<SUB>6</SUB>] (<B>1</B>) (pyH=pyridinium ion) and (pyH)<SUB>4</SUB>[Mo<SUB>2</SUB>O<SUB>3</SUB>S(NCS)<SUB>6</SUB>]·2H<SUB>2</SUB>O (<B>2</B>) have been determined from the diffractometer data. The <B>1</B> and <B>2</B> structures were refined by the least-squares method to <I>R</I> 0.041 and 0.064 for 2728 and 2349 non-zero reflections respectively. The two structures are isomorphous. Each Mo(V) ion has a distorted octahedral coordination, and two coordination octahedra share a common edge to form a binuclear complex. The binuclear complex contains a mirror plane through two bridging atoms. The two terminal oxo ligands on each Mo(V) are <I>cis</I> to each other and <I>cis</I> to the bridging oxo or sulfido. The Mo–N(NCS) bond length <I>trans</I> to the Mo–O<SUB>t</SUB> (terminal oxo) is <I>ca.</I> 0.1 Å longer than the other Mo–N(NCS) bond lengths, showing the large <I>trans</I> effect of the O<SUB>t</SUB> ligand.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Shibahara Takashi

  Department Of Chemistry Faculty Of Science Okayama University Of Science

• Kuroya Hisao

  Department of Chemistry, Okayama University of Science

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