XPS study of binuclear Mo(V) complexes with di-.MU.-oxo, .MU.-oxo-.MU.-sulfido, and di-.MU.-sulfido bridges.
スポンサーリンク
概要
- 論文の詳細を見る
X-Ray photoelectron spectroscopy (XPS) was applied to three binuclear molybdenum(V) complexes of di-μ-oxo-, μ-oxo-μ-sulfido-, and di-μ-sulfido-bis[(cysteinato)oxomolybdate(V)]<SUP>2−</SUP>, [Mo<SUB>2</SUB>(μ-O)<I><SUB>x</SUB></I>(μ-S)<I><SUB>y</SUB></I>O<SUB>2</SUB>(cys)<SUB>2</SUB>]<SUP>2−</SUP> (<I>x</I>=2, <I>y</I>=0; <I>x</I>=<I>y</I>=1; and <I>x</I>=0, <I>y</I>=2), and the electronic state for Mo atom of the (μ-O)<SUB>2</SUB> bridge, (μ-O, μ-S) bridge and (μ-S)<SUB>2</SUB> bridge complexes was studied. It has been found that the binding energy of the Mo 3d<SUB>5⁄2,3⁄2</SUB> peaks shifts to a lower value by at most 0.5 eV with increasing the number of μ-S bridges from 0 to 2. On the other hand, those of O 1s, C 1s, N 1s, and S 2s peaks are not significantly affected by bridge substitution. The change in the electronic state of Mo atoms is discussed in terms of the low electronegativity of the S atom.
- 公益社団法人 日本化学会の論文
著者
-
Shibahara Takashi
Department Of Chemistry Faculty Of Science Okayama University Of Science
-
Yamamoto Yoshihisa
Faculty Of Engineering Kyushu University
-
Takahashi Hideaki
Faculty of Engineering, Hokkaido University
関連論文
- Sulfur-Bridged Cubane-Type Molybdenum-Cadmium Clusters with Diethyldithiophosphato or Nitrilotriacetato Ligands
- Di- and Trinuclear Nickel(II) Complexes Containing Tripodal Hexadentate Ligands
- Preparation of Oxo-Bridged Dinuclear Iron(III) Complexes with One or Two O,O'-Bridged Optically Active Amino Acids
- Synthesis, Structure and Proton-Coupled Electron Transfer of μ-Oxo-μ-chloro and μ-Oxo-μ-alkoxo Dimeric Molybdenum(III) Ethylenediamine Complexes
- Redox Chemistry of Dinuclear Molybdenum Dithiolene Complexes. Interconversion of the Bridging Disulfide and Sulfides
- Photochromism of Dinuclear Tungsten Complexes with Disulfur and Ethylene-1,2-dithiolate Ligands
- Oxo-and Alkoxo-Bridged Dimeric Molybdenum(III) Ethylenediamine Complexes
- An Oxo- and Chloro-Bridged Dimeric Molybdenum(III) Ethylenediamine Complex
- Photochromism of Dinuclear Molybdenum Complexes with Disulfur and Ethylene-1, 2-dithiolate Ligands
- Syntheses and Characterization of Cubane-Type Clusters with Molybdenum-Iron-Sulfur (Mo_3FeS_4) or Molybdenum-Nickel-Sulfur (Mo_3NiS_4) Cores. X-Ray Structures of [Mo_3FeS_4(H_2O)_](CH_3C_6H_4SO_3)_4・7H_2O and [Mo_3FeS_4(H_2O)(NH_3)_9]Cl_4, and Discret
- A New Class of Bridged Diiron(III)Complex with a Schiff-base Bridge : Structure and Magnetic Properties of Di-N, N'-trimethylene bissalicylidenimine(bis-N, N'-trimethylenebissalicylideniminato)iron(III)
- Urinary Excretion of Mercury from Mice Exposed to Metallic Mercury Vapor Determined with NTA Complex
- Cobalt(III) Complexes with [N_6-nX_n]-Type Ligands. VIII. Perparation and Properties of Iaomers of the (Salicylaldoximato)(triethylenetetramine)cobalt(III) Complexes and Crystal Structure of cis-β_1-(RS, SR)-[Co(salal)(trien)]Cl・(CH_3COCH_3)・2H_2O
- Sulfur-Bridged Double Cubane-Type Tungsten-Nickel Mixed-Metal Cluster. Synthesis and X-Ray Structrue of [{W_2NiS_4(H_2O)_9}_2](CH_3C_6H_4SO_3)_8・20H_2O
- Reaction of a Sulfur Bridged Incomplete Cubane-Type Tungsten Cluster with Acetylene: Formation of Three Carbon-Sulfur Bonds
- How Do Ethane-Type Molecules Avoid Eclipsing When Forced as Such? The Case of 7, 8, 9, 10-Tetrachloro-1, 1-dimethyl-1, 2, 6, 10b-tetrahydro-6, 10b-o-benzenoaceanthrylene
- Sulfur-Bridged Incomplete Cubane-Type Iminodiacetato Molybdenum Clusters: Geometrical Isomers and Their Isomerization
- Fluorescent Tin(IV) Complexes with Schiff Base Ligands
- Fast-Acting Valves for Use in Shock Tubes : Part 2, Formation of shock waves
- Fast-Acting Valves for Use in Shock Tubes : Part 1, Construction and their characteristics
- Three-Dimensional Flow Measurement by Means of Multisampling Scan with a Small Pressure Sensor : Series B : Fluid Engineering, Heat Transfer, Combustion, Power, Thermophysical Properties
- Magnetic Susceptibility Analysis of Mixed Metal Cubane-Type Cluster complexes, [tetra-μ_3-thio-tris {tri(aqua)molybdenum}aquairon] (4+) -toluensulfonate heptahydrate and [tetra-μ_3-thiotris {tri(aqua)molybdenum} aquanickel] (4+) p-toluensulfonate heptahyd
- Uptake of Carbon Monoxide by a Sulfur-Bridged Molybdenum-Nickel Cluster. Synthesis and Structure of [Mo_3NiS_4(CO)(H_2O)_9]^
- Magnetic properties of some molybdenum(V) dimeric coordination compounds with terminal oxo-ligands and di-.MU.-oxo-, di-.MU.-sulfido- or .MU.-oxo-.MU.-sulfido- bridges.
- Evaluation of the Degree of Mixing of Combinations of Dry Syrup, Powder, and Fine Granule Products in Consideration of Particle Size Distribution Using Near Infrared Spectrometry
- Cobalt(III) complexes with quadridentate ligands. VIII. The preparation and properties of cis-.BETA.1 and .BETA.2-isomers of the thiosalicylato(quadridentate amine)cobalt(III) complexes.
- The preparation and X-ray structures of di-.MU.-sulfido- and .MU.-oxo-.MU.-sulfido-bis(tris(isothiocyanato)oxomolybdate(V)) ions.
- タイトル無し
- Fluorescent Tin(IV) Complexes with Schiff Base Ligands : Synthesis, Structures, and Fluorescence Lifetime
- Cobalt(III) complexes with quadridentate ligands. IX. High-resolution solid-state 13C CP/MAS NMR spectra of the salicylato-, carbonato-, dichloro-, and dinitro(quadridentate amine)-cobalt(III) complexes.
- Bridges in polynuclear complexes. II. An X-ray investigation of the coordination of silver ion to the .MU.-peroxo bridge of a dinuclear Cobalt(III) complex.
- Bridges in polynuclear complexes. I. The reaction and reaction products of .MU.(NH2,O2) dicobalt complexes with nitrites.
- Formation of hydrogen peroxide by two-stage acid hydrolysis of trans(NO2,O2)-[.MU.-peroxo-bis{nitrtobis(ethylenediamine)-cobalt(III)}] and reaction kinetics.
- Raman and infrared spectra of .MU.-O2 dicobalt(III) complexes.
- Paramagnetic cobalt(III) complexes with organic ligands. VI. An X-ray photoelectron spectroscopic study.
- Ylide-metal complexes. III. Preparation and properties of gold(I) complexes of alkylidenetriphenylphosphoranes and -arsoranes.
- The preparation and properties of ethylenediamine(8-quinolinolato)cobalt(III) complexes.
- XPS study of binuclear Mo(V) complexes with di-.MU.-oxo, .MU.-oxo-.MU.-sulfido, and di-.MU.-sulfido bridges.
- Ylide-metal complexes. XIII. An X-ray photoelectron spectroscopic study of bis(dimethylsulfoxonium methylide)gold chloride.
- Magnetic properties of molybdenum (IV) trinuclear coordination compounds, Ba(Mo3O3S(Hnta)310H2O and Ca1.5(Mo3S4(Hnta)2(nta))12H2O.
- Preparation and structure of .MU.-oxalato-bis{.MU.-oxo-.MU.-sulfido-bis-((oxalato)oxomolybdate(V))} complex, K6({Mo2O3S(ox)2}2(ox))10H2O.
- Magnetism and electronic structure of a cubane-type Mo4S4 cluster.
- Magnetic properties of (.MU.-(ethylenediaminetetraacetato)-di-.MU.-sulfido-bis{oxomolybdate(V)})2- and (.MU.-(ethylenediaminetetraacetato)-di-.MU.-oxo-bis{oxomolybdate(V)})2- ions.
- Paramagnetic cobalt(III) complexes with organic ligands. X The preparation and properties of radical diamminebis(5-nitrosalicylideneaminato)cobalt(III) complex and biradical diamminebis(5-nitrosalicylideneaminato)cobalt(II) complex.
- A new synthetic route to hexachloromolybdate(III). An X-ray structure of (NH4)3(MoCl6).
- Preparation and properties of ".BETA.1 and .BETA.2"-isomers of the salicylato(triethylenetetramine)cobalt(III) complex.
- Paramagnetic cobalt(III) complexes with organic ligands V. The isolation and properties of salts of the paramagnetic bis(2,2'-bipyridine)(5-nitrosalicylato)cobalt(III) and of the paramagnetic ".BETA.1 and .BETA.2"-isomers of the 5-nitrosalicylato(triethyl
- Cobalt(III) complexes with quadridentate ligands. V. The preparation and properties of paramagnetic and diamagnetic cis-.BETA.2-isomer of the 5-nitrosalicylato(quadridentate amine)cobalt(III) complexes.
- Paramagnetic cobalt(III) complexes with organic ligands. VII. The isolation and properties of paramagnetic tetraammine-(5-nitrososalicylato)cobalt(III) complexes.
- Cobalt(III) complexes with (N6-nXn) type ligands. IV. The preparation and properties of tetraammine(salicylideneaminato)cobalt(III) and diamminebis(salicylideneaminato)cobalt(III) complexes.
- Ylide-metal complexes. IV. The preparation and properties of IIb-group metel (Zn, Cd, Hg) complexes of alkylidenetriphenylphosphoranes.
- Cobalt(IV) ammine complexes with 5-nitrosalicylato or similar ligands. IV. Preparation, 1H-NMR, 13C-NMR, and IR spectra.
- Cobalt(III) complexes with quadridentate ligands. VII. The preparation and properties of the salicylato or dichloro[tris(2-aminoethyl)amine]cobalt(III) complexes and the related complexes.
- Cobalt(III) complexes with (N6-nXn)-type ligands. V. The preparation and properties of N,N'-disalicylidene-substituted quadridentate amine cobalt(III) complexes.
- Cobalt(III) Complexes with (N6-nXn)-Type Ligands. VII. Preparation and Properties of Isomers of the (Salicylamidato) cobalt(III) Complexes with Tris(2-aminoethyl)amine, Triethylenetetramine, and Ethylenediamine Ligands.
- Ylide-metal complexes. VI. The preparation and properties of IVA-group metal (Ge,Sn,Pb) complexes of alkylidenetriphenylphosphoranes.
- Ylide-metal complexes. VII. The preparation and properties of IIA group metal(Be,Mg) and IIIA group metal(Al,Ga,In) complexes of alkylidenetriphenylphosphoranes.