Ylide-metal complexes. VI. The preparation and properties of IVA-group metal (Ge,Sn,Pb) complexes of alkylidenetriphenylphosphoranes.
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(Triphenylphosphonium alkylide)triphenylmetal chloride [(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>\overset+PCHR–M(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>]Cl<SUP>−</SUP> (R: H, Me, <I>i</I>-pr; M: Ge, Sn, Pb) and (triphenylphosphoniumalkylide)metal chloride [(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>\overset+PCHR]<I><SUB>n</SUB></I>MCl<I><SUB>n</SUB></I><SUP>−</SUP>, (M=Ge,<I>n</I>= 4; M=Pb, <I>n</I>=2) have been isolated from a reaction mixture of alkylidenetriphenylphosphoranes and IVA-group metal compounds. The ylide in [(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>\overset+PCH<SUB>2</SUB>–Pb(C<SUB>6</SUB>H<SUB>5</SUB>)<SUB>3</SUB>]Cl<SUP>−</SUP> is bonded to the lead atom through the carbanionic donor atom.
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