The Crystal Structure of (+)<SUB>589</SUB>-Dicyanobis(ethylenediamine)cobalt(III) Chloride Monohydrate

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概要

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• The crystal structure of (+)<SUB>589</SUB>-[Co(CN)<SUB>2</SUB>en<SUB>2</SUB>]Cl·H<SUB>2</SUB>O has been determined from three-dimensional X-ray photographic data. The crystals are monoclinic, with the lattice constants of <I>a</I>=8.15(1), <I>b</I>=11.69(2), <I>c</I>=6.61(1) Å, and β=107.1(2)°, and with the space group of <I>P</I>2<SUB>1</SUB> containing two formula units in the cell. The structure was solved by a conventional Fourier technique and was refined by the least-squares method to an <I>R</I> factor of 0.114. The absolute configuration of the complex ion can be denoted as <I>Λ</I>(λλ); this is in accordance with the assignment made by Mason <I>et al.</I> The complex ion has an approximately two-fold axis, and both of the ethylenediamine chelate rings are of the <I>ob</I>-conformation.

• 公益社団法人 日本化学会の論文

著者

• Matsumoto Keiji

  Department Of Applied Physics Graduate School Of Engineering Yokohama National University

• Kuroya Hisao

  Department of Chemistry, Okayama University of Science

• Ooi Shun'ichiro

  Department of Chemistry, Faculty of Science, Osaka City Univetsity

• Matsumoto Keiji

  Department of Chemistry, Faculty of Science, Osaka City Univetsity

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