Kinetic and equilibrium studies on substitution reactions of the chlorobis(.BETA.-diketonato)manganese(III) complexes with other .BETA.-diketones.
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概要
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The MnCl(β-dik)<SUB>2</SUB> complexes, where β-dik stands for an anion of acetylacetone, benzoylacetone, and dibenzoylmethane, were confirmed to have the five-coordinate structure in dichloromethane and their adduct formation constants with various donor solvents were measured. Equilibria and kinetics of substitution reactions of MnCl(β-dik)<SUB>2</SUB> with other β-diketones were determined by the spectrophotometric method and the mechanism for these reaction is proposed.
- 公益社団法人 日本化学会の論文
著者
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ITO Yoshiaki
Department of Agro-Bioscience, Faculty of Agriculture, Iwate University
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Kawaguchi Shinichi
Department Of Fundamental Energy Science Graduate School Of Energy Science Kyoto University
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