The synthesis of 4,5-ethylenedithio-4',5'-vinylenedithiotetrathiafulvalene(EVT) and its methyl and dimethyl derivatives (EMVT, EDMVT), and the molecular and crystal structures of EVT.

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概要

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• New donor molecules, 4,5-ethylenedithio-4′5′-vinylenedithiotetrathiafulvalene (EVT) and its methyl and dimethyl derivatives (EMVT and EDMVT), were synthesized for the study of conducting organic salts. They are unsymmetrical TTF derivatives possessing moieties of both BEDT-TTF and bis(vinylenedithio)tetrathiafulvalene (VT) or its methyl and dimethyl derivatives. Their oxidation potentials were measured and then compared with those of the related donor molecules. The X-ray crystal structure analysis of EVT revealed that its molecular and crystal structures are very close to that of BEDT-TTF.

• 公益社団法人 日本化学会の論文

著者

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Harada Shigeharu

  Department Of Applied Biology Kyoto Institute Of Technology

• Shirota Yasuhiko

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Nakano Hideyuki

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Nogami Takashi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Miyawaki Kenji

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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