The Crystal and Molecular Structure of Dimethyltin Chloride <I>N</I>,<I>N</I>-Dimethyldithiocarbamate

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概要

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• The molecular structure of dimethyltin chloride <I>N</I>,<I>N</I>-dimethyldithiocarbamate, [(CH<SUB>3</SUB>)<SUB>2</SUB>-SnCl(S<SUB>2</SUB>CN(CH<SUB>3</SUB>)<SUB>2</SUB>)], has been determined from three-dimensional X-ray diffraction data. The unit-cell dimensions are <I>a</I>=12.67, <I>b</I>=7.64, <I>c</I>=12.11 Å, and β=110.3°. The space group is <I>P</I>2<SUB>1</SUB>/<I>c</I>. Four formula units are contained in a unit-cell. The structure was established by the heavy-atom method. The coordination around the tin atom is a distorted trigonal bipyramid with the following bond distances: Sn–C, 2.17(5) and 2.20(5) Å, Sn–Cl, 2.46(1) Å and Sn–S, 2.48(1) and 2.79(1) Å. Two methyl groups are both in equatorial positions.

• 公益社団法人 日本化学会の論文

著者

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department Of Life Science Faculty Of Science Himeji Institute Of Technology

• Kakudo Masao

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Kimura Toshihide

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Furue Kenji

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yasuoka Noritake

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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