The crystal and molecular structure of N-ethylcarbazole.

スポンサーリンク

概要

• 論文の詳細を見る

• <I>N</I>-Ethylcarbazole crystallizes in the orthorhombic system, space group Pbca with fairly large unit cell dimensions of <I>a</I>=7.971(1), <I>b</I>=24.615(3), <I>c</I>=56.587(5) Å, <I>D</I><SUB>m</SUB>=1.17 g cm<SUP>−3</SUP>, <I>D</I><SUB>c</SUB>=1.168 g cm<SUP>−3</SUP> for <I>Z</I>=40. The structure was solved by the direct method and refined anisotropically by the least-squares procedure, <I>R</I>=0.062 for 5134 non-zero reflections. Five crystallographically independent molecules are not different from each other, the carbazole group is planar, and the ethyl group attached to the nitrogen atom is almost perpendicular to the carbazole ring. In the crystal, each carbazole ring makes a similar angle with the a axis [52 to 55°].

• 公益社団法人 日本化学会の論文

著者

• Kai Yasushi

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department Of Life Science Faculty Of Science Himeji Institute Of Technology

• Kimura Toshihiko

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

関連論文

• First Determination of the Inhibitor Complex Structure of Human Hematopoietic Prostaglandin D Synthase
• Structural Basis for the Decarboxylation of Orotidine 5'-Monophosphate (OMP) by Plasmodium Falciparum OMP Decarboxylase
• 2P149 A novel supramolecular assembly and intermolecular electrontransfer process of Hyphomicrobium Cu-containing nitrite reductase(33. Redox enzyme,Poster Session,Abstract,Meeting Program of EABS & BSJ 2006)
• Structural Reorganization of the Copper Binding Site Involving Thr^ of Mavicyanin from Cucurbita pepo medullosa (Zucchini) upon Reduction
• Crystallization and Preliminary X-Ray Crystallographic Studies of Trypanosoma brucei Prostaglandin F_ Synthase
• Crystal Structure of Long Alkyl 3-(Thymin-1-yl)propionates: Style of Hydrogen Bonding and Dependence on the Alkyl Chain Length
• Structures and Photodimerizations of 1-Alkylthymine Crystals Obtained from N,N-Dimethylformamide
• Photodimerization of 1-Alkylthymines Crystallized from Acetonitrile Solution
• Crystal Structures of Wild-Type and Mutant Plastocyanins from a Higher Plant, Silene^1
• Type1 Cu Structure of Blue Nitrite Reductase from Alcaligenes xylosoxidans GIFU 1051 at 2.05 Å Resolution: Comparison of Blue and Green Nitrite Reductases
• Crystallographic Studies on a Family B DNA Polymerase from Hyperthermophilic Archaeon Pyrococcus kodakaraensis Strain KOD1^1
• Blue Phosphorescence of the Novel Dinuclear Gold(I) Complex Bridged by 1, 3-Benzenedithiolate in Solution
• Aggregation through the Quadrupole Interactions of Gold(I) Complex with Triphenylphosphine and Pentafluorobenzenethiolate
• Temperature-Dependent Solid-state Luminescence and Reversible Phase Transition of (n-Bu_4N)[Au(SC_6H_3-3, 5-Me_2)_2]
• Highly Crowded trans-Olefin. Molecular Structure of trans -1, 2-Bis{meso-[nickel(II)octaethylporphyrinyl]}ethene
• Reversible Photodimerization of Ester Derivatives of Thymine Having Long Alkyl Chains in Solid Film
• Synthesis of Binuclear Ligands Possessing Two Discrete Multidentate N-Heterocyclic Podand Coordination Sites and Their Bimetallic Nickel(II) Complexes
• Photoreactive and Inactive Crystals of 1-Alkylthymine Derivatives
• The Role of Structural Intersubunit Microheterogeneity in the Regulation of the Activity in Hysteresis of Ribulose 1,5-Bisphosphate Carboxylase/Oxygenase^1
• Roles of Functional Loops and the C-Terminal Segment of a Single-Stranded DNA Binding Protein Elucidated by X-Ray Structure Analysis
• Crystallization and Preliminary Crystallographic Studies of Ribulos 1,5-Bisphosphate Carboxylase/Oxygenase from a Red Alga, Galdieria partita, with a High Specificity Factor
• Electrochemical and Luminescent Properties of New Mononuclear Ruthenium(II) and Binuclear Iridium(III)-Ruthenium(II) Terpyridine Complexes
• Electrochemical and Phosphorescent Properties of New Ir(III) Complexes Coordinated by Various Bipyridine Derivatives
• Synthesis, Structures and Characterization of the Dinuclear Nickel(II) Complexes Containing N,N,N',N'-Tetrakis[(1-ethyl-2-benzimidzolyl)-methyl]-2-hydroxy-1,3-diaminopropane and their Ure Complexes Relevant to the Urease Active Site
• Syntheses, Structures and Solution Dynamics of Anionic 5-Coordinate Pt(II) Complexes with Halide
• Syntheses, Structures, and Properties of the Dinuclear Copper(II) and Nickel(II) Complexes Bridged by an Alkoxide and a Pyridazine or a Phthalazine
• Structures of Bis(5,5-diphenylhydantoinato)copper(II) Complexes with Primary Amines Involving Square Pyramidal CuN_40 Chromophores
• The Synthesis, Antileukemic Activity, and Crystal Structures of Indirubin Derivatives
• Structure Determination of the Constitutive 20S Proteasome from Bovine Liver at 2.75 Å Resolution^1
• New Crystal Forms and Low Resolution Structure Analysis of 20S Proteasomes from Bovine Liver
• Characterization of a Small Metalloprotease from Streptomyces caespitosus with High Specificity to Aromatic Residues
• Structure of the Zinc Endoprotease from Streptomyces caespitosus^1
• The Stablization of Dioxomolybdenum(VI) Dithiolene Complex by the Electron Withdrawing Substituent on the Dithiolene Ligand: Comparison of Reactivities of Monooxomolybdenum(IV) Complex with R_2S_2C_2(R= -CN and -COOMe) Ligands as Models of Molybdenum Oxid
• Crystal Structure of Pyridine [24-{3, 3-bis(carbethoxy)propyl}-8-quinolinol-C, N, O]platinum(II) and Characterization of (Pt)C-Bonding Substituents
• Laser Irradiated Growth of Protein Crystal
• Enzymatic Characterization of 5-Methylthioribose 1-Phosphate Isomerase from Bacillus subtilis
• The Crystal Structure of the Polymerization Catalyst of Acetaldehyde and Its Derivatives. IV. The Crystal and Molecular Structure of Dimethylaluminum N-Phenylbenzimidate-O-(Trimethylaluminum)-Acetaldehyde Complex, [(CH3)2
• The Crystal Structure of the Polymerization Catalyst of Acetaldehyde and Its Derivatives. III. The Crystal and Molecular Structure of the Bis(dimethylaluminum N-Phenylbenzimidate-Acetaldehyde) Complex, [(CH3)2Al·O·C(C6
• The Crystal Structure of the Polymerization Catalyst of Acetaldehyde and Its Derivatives. II. The Crystal and Molecular Structure of the Trimethylamine Oxide Adduct of Dimethylaluminum N-Phenylbenzimidate, [(CH3)2Al·O·C(C
• The crystal and molecular structure of anhydrous zinc 8-quinolinolate complex, (Zn(C9H6NO)2)4.
• The crystal structure of N-methylviologenium 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide,((CH3NC5H4C5H4NCH3)2+(C10N6)2-).
• The crystal and molecular structures of 4-ethyl-3,5-bis(phenylimino)-1,2,4-dithiazolidine and 2-ethyl-4-phenyl-5-phenylimino-1,2,4-thiadiazolidin-3-thione.
• Molecular structures of (2)(2,5)(7,7,8,8-tetracyanoquinodimethano)(2)paracyclophane and 14,17-dimethoxy(2)(2,5)(7,7,8,8-tetracyanoquinodimethano)(2)paracyclophane.
• The crystal and molecular structure of N-ethylcarbazole.
• The crystal and molecular structure of 2,3,6,8,9-pentaphenyl-1-thia-6-azaspiro(4.4)nona-2,8-diene-4,7-dione.
• The crystal structure of 2,11,20-trithia(3.3.3)(1,2,4)(1,3,5)cyclophane and molecular structures of unsymmertically tris-bridged (2.2.2)(1,2,4)(1,3,5) and (2.2.2)(1,2,4)(1,2,5)cyclophanes, estimated by molecular conformational analysis.
• Crystal and Molecular Structure of Di-μ-chloro-bis(π-1-ethoxycarbonyl-2-hydroxyallyl)dipalladium(II)
• The crystal and molecular structure of syn-(2.2)(1,4)-anthracenophane and its photoisomer.
• The molecular structure of bromo(ethyl)((-)-sparteine)magnesium(II), a catalyst for the asymmetric-selective polymerization of racemic methacrylates.
• The crystal and molecular structure of 2:2 complex of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol (DD) with 1-methyl-2-(3-pyridyl)pyrrolidine (nicotine).
• The crystal and molecular structure of strontium bis(thiocyanate)-hexaethylene glycol (1/1)
• The crystal structure of (acetylacetonato)bis(diethylamine)palladium(II) acetylacetonate at -170.DEG.C.
• Three-dimensionally-modified tetracyanoquinodimethanes and their charge-transfer complexes with tetrathiafulvalene derivatives having a wide range of ionicity.
• Stopped-flow small-angle X-ray scattering study on the acid-denaturation of Taka-amylase A.
• The molecular structure of the heterodinuclear organometallic complex of platinum and tungsten, phenyl(1,5-cyclooctadiene)platinum-tricarbonyl(.ETA.5-cyclopentadienyl)tungsten.
• The Crystal Structure of 2,4,6-Triphenylpyrylium-1,1,3,3-tetracyanopropenide, [(C23H17O)+·(C7HN4)−]
• The crystal and molecular structures of dichloro-1,2-bis(di-t-butylphosphino)-ethaneplatinum(II) and its chlorobenzene solvate.
• The crystal and molecular structure of (acetylacetonato)(carboxymethyl)-(triphenylphosphine)palladium(II).
• Chemistry of dienyl anions. II. Crystalline bis(dienyl)magnesium. Selective dienylation and structure in solution and in the solid state.
• The crystal and molecular structure of 6-bromo(2.2)paracyclo(4,8)(2.2)metaparacyclophane.
• The molecular structure of tricarbonyl(triple-layered[2.2]paracyclophane)chromium at -95.DEG.C(monoclinic form) and -160.DEG.C(triclinic form).
• The Crystal Structure of 1-Ethyl-2-methylquinolinium Iodide, [(C12H14N)+·I−]
• Chemistry of dienyl anions. III. Crystalline bis(2,4-pentadienyl)metal compounds of Be and Zn. Terminally .SIGMA.-bonded structure and fluxional 1,5-rearrangement.
• The crystal and molecular structure of tetracyclo[6.4.3.0.02,7]pentadec-4-en-13-one.
• Molecular structure of (2)(2,5)(7,7,8,8-tetracyanoquinodimethano)-(2)(1,4)naphtalenophane.
• Molecular Structures of Trichlorovinyl(p-tolyl)nickel(II) Complex, and Its Thermal and Photo Isomerization Products.
• The molecular structure of 1-phenoxy-1,2,2a,8b-tetrahydrocyclobuta[a]naphthalene-8b-carbonitrile.
• The crystal and molecular structures of trans-dichlorobis(dimethylneomenthylphosphine)palladium(II) and trans-dichlorobis(dimethylmenthylphosphine)palladium(II), asymmetric hydrosilylation catalysts of olefin.
• The molecular structures of (+)-6-benzylsparteine, (ethyl)(bromo)((+)-6-benzylsparteine)magnesium(II), and dibromo((+)-6-benzylsparteine)magnesium(II). Structure and reactivity of the Grignard reagent-(-)-sparteine derivative complexes for asymmetric sele
• The molecular structures of thiomethoxymethylbis(triphenylphosphine)-palladium hexafluorophosphate and perchlorate at -160 .DEG.C.
• The Crystal and Molecular Structure of Dimethyltin Chloride N,N-Dimethyldithiocarbamate
• The crystal and molecular structure of 12-bromo(2.2)(2.2)triple-layered paracyclophane.
• Conformational analysis of methacrylates by IR and 1H NMR spectroscopies.
• The crystal and molecular structure of diphenyl-2-pyridylmethyl methacrylate.
• The molecular structures of (t-butyl)(chloro)((-)-sparteine)magnesium(II) and dichloro((-)-sparteine)magnesium(II).
• The X-ray and NMR studies on the regio- and stereoselective courses for insertion of ketones into the s-cis- and s-trans-diene complexes of zirconium leading to (Z)-1,2-oxazirconacyclohept-4-enes.
• The structure and reactivity of (Zn(OMe)2 (EtZnOMe)6).
• The crystal and molecular structure of (acetylacetonato)-(diacetylmethyl)(diethylamine)palladium(II).
• The crystal and molecular structure of dichloro[1,3-bis(di-t-butylphosphino)propane]platinum(II) chlorobenzene solvate.
• The crystal and molecular structures of three (acetylacetonato)-organoantimony(V) compounds, [(acac)RnSbX4-n].
• The X-ray structure determination of heptaethylene glycol-Sr(SCN)2.
• The crystal and molecular structures of trans-bis(trimethylphosphine)[1,2-bis(methoxycarbonyl)vinyl](phenylethynyl)palladium(II).
• The molecular structure of a Schiff base complex, [N,N'-ethylenebis-(1-phenyl-2-imino-1-butanonato)](acetonitrile)-manganese(III) perchlorate.
• The crystal and band electronic structures of bis(4,5-ethylenedithio-4',5'-(vinylenedithio)tetrathiafulvalenium)hexafluorophosphate, and hexafluoroarsenate (EVT2PF6 and EVT2AsF6).
• The synthesis of 4,5-ethylenedithio-4',5'-vinylenedithiotetrathiafulvalene(EVT) and its methyl and dimethyl derivatives (EMVT, EDMVT), and the molecular and crystal structures of EVT.
• Synthesis and structural properties of copper complexes toward the active center model of galactose oxidase
• The Molecular Structure of the Reaction Product from Sulfurdiimide and Diphenylketene
• The crystal and molecular structure of 1:2 molecular complex of 1,4-diazabicyclo[2.2.2]octane(DABCO) with p-cresol.
• Coenzyme models. 50. Elavin activation by intramolecular acid catalysis at N(1) position.
• The Crystal Structure of 1,4-Bis(p-bromophenoxy) butane
• The Crystal Structure of Quinolinium 2-Dicyanomethylene-1,1,3,3-tetracyanopropanediide, [2(C9NH8)+·(C10N6)2−]
• The Crystal and Molecular Structure of trans-Bis(trimethylphosphine)propynyl-1-(4′-dicyanomethylene-cyclohexa-2′-5′-dien-1-ylidenl-3,3-dicyano-2-methyl-prop-2-en-1-ylplatinum, a Reaction Product of trans-Bis(trimethylphosphine)bis(propynyl)p
• X-ray molecular structure of 1-cyano-7,8-benzo-11-oxatricyclo-[4.2.2.12,5]undeca-3,7,9-triene.
• The crystal and molecular structures of bis[1,2-bis(methylthio)vinylenedithio]-tetrathiafulvalene (TMTVT).
• The crystal and molecular structure of inner triple-layered paracyclophanequinone.
• The crystal and molecular structure of two triple-layered metaparacyclophanes.
• C,O-chelates of the trifluoroacetylacetonate dianion with palladium(II). Molecular structure of (Pd(tfac(2-)-C,O)(PPh3)(2,6-Me2-py))
• The crystal structure of bis(acetylacetonato)platinum(II) benzene solvate.
• Crystallization and Preliminary X-Ray Crystallographic Studies of Trypanosoma brucei Prostaglandin F2.ALPHA. Synthase.
• Type 1 Cu Structure of Blue Nitrite Reductase from Alcaligenes xylosoxidans GIFU 1051 at 2.05 .ANGS. Resolution: Comparison of Blue and Green Nitrite Reductases.

もっと見る 閉じる

スポンサーリンク