The crystal and molecular structure of strontium bis(thiocyanate)-hexaethylene glycol (1/1)

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概要

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• The molecular structure of strontium bis(thiocyanate)-hexaethylene glycol(1/1) has been determined from single crystal X-ray diffraction data(3121 observed reflections): triclinic, space group P\bar1, <I>a</I>=12.086(4), <I>b</I>=8.732(2), <I>c</I>=10.628(2) Å, α=80.88(2), β=101.99(3), γ=100.55(2)°, <I>D</I><SUB>m</SUB>=1.48, <I>D</I><SUB>c</SUB>=1.48 g cm<SUP>−3</SUP> for <I>Z</I>=2. The central Sr ion is coordinated by seven O atoms from the hexaethylene glycol moiety and two N atoms from the SCN groups; the Sr–O distances range from 2.603(5) to 2.750(5), while the Sr–N distances are 2.628(8) and 2.634(8) Å. The hexaethylne glycol moiety assumes a GT<SUB>2</SUB>\barGT<SUB>2</SUB>GT<SUB>2</SUB>\barGT<SUB>2</SUB>GTG<SUB>2</SUB> conformation.

• 公益社団法人 日本化学会の論文

著者

• Miki Kunio

  Department Of Chemistry Graduate School Of Science Kyoto University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department Of Life Science Faculty Of Science Himeji Institute Of Technology

• Yamaguchi Iwao

  Department Of Cardiology

• Miki Kunio

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yamaguchi Iwao

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yasuoka Noritake

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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