The crystal structure of (acetylacetonato)bis(diethylamine)palladium(II) acetylacetonate at -170.DEG.C.

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概要

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• The crystal structure of [{Pd(acac)(NHEt<SUB>2</SUB>)<SUB>2</SUB>}<SUP>+</SUP>(acac)<SUP>−</SUP>] at −170°C was determined by means of X-ray diffraction. The crystal belongs to monoclinic system: <I>a</I>=13.905(3), <I>b</I>=12.901(4), <I>c</I>=12.205(3) Å, β=96.28(2)°, space group I2/c with <I>Z</I>=4. The structure was established by the heavy atom method and refined anisotropically by the least-squares procedure; <I>R</I>=0.044 for 1558 non-zero reflections. Both the {Pd(acac)(NHEt<SUB>2</SUB>)<SUB>2</SUB>}<SUP>+</SUP> cation and (acac)<SUP>−</SUP> anion lie on the crystallographic two-fold axis. The cation and anion lying on the same two-fold axis are bound together by two hydrogen bonds [N–H···O(2)=N′–H′···O(2′)=2.871(4) Å] to form an ion-pair. Two ion-pairs mutually related by the crystallographic center of symmetry make a packing unit of the crystal.

• 公益社団法人 日本化学会の論文

著者

• Miki Kunio

  Department Of Chemistry Graduate School Of Science Kyoto University

• Kai Yasushi

  Department Of Applied Chemistry Faculty Of Engineering Osaka University

• Kasai Nobutami

  Department Of Applied Biological Science Tokyo University Of Science

• Yasuoka Noritake

  Department Of Life Science Faculty Of Science Himeji Institute Of Technology

• Sei Tsuyoshi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Kotake Shoji

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Miki Kunio

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Yasuoka Noritake

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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