Monophotonic ionization mechanism of N,N,N',N'-tetramethyl-1,6-pyrenediamine in acetonitrile solution.
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概要
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Monophotonic ionization of <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetramethyl-1,6-pyrenediamine (TMPDA) in acetonitrile was studied by means of ns laser photolysis and transient photocurrent measurement. The time dependences of the absorption of TMPDA cation radical and of the photocurrent were different. Photoionization thus occurs through an ionpair state.
- 公益社団法人 日本化学会の論文
著者
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Shirota Yasuhiko
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Kobayashi Naoki
Department Of Applied Physics And Chemistry The University Of Electro-communications
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Mikawa Hiroshi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Sumitani Minoru
Institute for Molecular Science
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Nogami Takashi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Aoki Masaaki
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Mizuhara Toshio
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Akashi Takao
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Kobayashi Naoki
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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