Reduction of Acyl Enolates of α-Substituted β-Keto Esters by Bakers' Yeast(Organic Chemistry)
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概要
- 論文の詳細を見る
Enol esters of 2-substituted-3-oxoalkanoates of (Z)-configuration were reduced by bakers' yeast to chiral 2-substituted-3-hydroxyalkanoates. The syn-selectivities of this reaction increased compared with those of the reduction of the corresponding racemic keto esters. The reaction may proceed via an asymmetric hydrolysis of the enol esters, followed by the reduction of the resulting carbonyl group.
- 社団法人日本農芸化学会の論文
- 1990-02-23
著者
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KOBAYASHI Naoki
Department of Physics, Chuo University
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Ohta Hiromichi
Department Of Applied Chemistry School Of Engineering Nagoya University
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Sugai Takeshi
Department Of Chemistry Faculty Of Science And Technology Keio University
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Sugai Takeshi
Department Of Agricultural Chemistry The University Of Tokyo
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Kobayashi Naoki
Department Of Orthopaedic Surgery Dokkyo University School Of Medicine
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Kobayashi Naoki
Department Of Chemistry Faculty Of Science And Technology Keio University
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Kobayashi Naoki
Department Of Applied Physics And Chemistry The University Of Electro-communications
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