Degradation of Derivatives of N-Acetyl-D-glucosamine by Rhodococcus rhodochrous IFO 15564 : Substrate Specificity and Its Application to the Synthesis of Allyl α-N-Acetyl-D-glucosaminide
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概要
- 論文の詳細を見る
The substrate specificity was studied for the metabolic degradation of N-acetyl-D-glucosamine (GlcNAc) derivatives by Rhodococcus rhodochrous IFO 15564 which possesses N-acetyl-D-glucosamine deacetylase as a key-step enzyme. This microorganism degraded a wide range of substrates with modified N-acyl groups. The metabolizing activity of this strain became low to the substrates substituted at 1,3,4,6-positions of GlcNAc, and GlcNAc itself was suggested to be metabolized via an open-chain aldehyde form. Based on these results, a simplified procedure for the isolation of allyl α-N-acetyl-D-glucosaminide from an α, β-anomeric mixture was developed by selectively hydrolyzing the β-anomer with Jackbean β-N-acetyl-D-glucosaminidase and subsequently degrading the resulting N-acetyl-D-glucosamine in the reaction mixture with this microorganism.
- 社団法人日本農芸化学会の論文
- 1998-08-23
著者
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須貝 威
慶應義塾大学理工学部
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Ohta H
Okayama Univ. Okayama
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Ohta H
Department Of Bioscience And Informatics Center For Life Science And Technology Keio University
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Ohta H
Department Of Chemistry Faculty Of Science And Technology Keio University
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Ohta H
Department Of Chemistry Keio University
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Ohta Hiromichi
Department Of Chemistry Faculty Of Science And Technology Keio University
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Ohta H
Keio Univ. Kanagawa
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Sugai Tomoharu
Department Of Bioresource Engineering Faculty Of Agriculture Yamagata University
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SUGAI Takeshi
Department of Chemistry, Faculty of Science and Technology, Keio University
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KUBOKI Atsuhito
Department of Chemistry, Keio University
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Sekiguchi Takahiro
Department Of Chemistry Keio University
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KOMIYA Ryosuke
Department of Chemistry, Keio University
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KATSURAGI Kenji
Department of Chemistry, Keio University
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Ohta H
Department Of Food And Nutrition Nakamura Gakuen University
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Ohta Hiromichi
Department Of Applied Chemistry School Of Engineering Nagoya University
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Komiya Ryosuke
Department Of Chemistry Keio University
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Okazaki Hanako
Department Of Chemistry Keio University
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Kuboki Atsuhito
Department Of Chemistry Keio University
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Kuboki Atsuhito
Department Of Biochemistry Okayama University Of Science
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Sugai Takeshi
Department Of Agricultural Chemistry The University Of Tokyo
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Katsuragi Kenji
Department Of Chemistry Keio University
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