Syntheses of Highly Oxygen-functionalized Derivatives of Dihydrodihydroxyphthalic Acid in Enantiomerically Enriched Forms
スポンサーリンク
概要
- 論文の詳細を見る
Starting from dihydrodihydroxyphthalic acid (DDP), (1R, 2S, 5R, 6S)-(-)-3, 4-bis(benzyloxymethyl)-5-hydroxy-8, 8-dimethyl-6, 8-dioxabicyclo[4.3.0]non-3-en-2-yl chloroacetate (>95%e.e.), a highly oxygen-functionalized derivative, was prepared by a combination of chemical and enzymatic reactions.The key step for asymmetrization was hydrolysis of the corresponding meso bis-chloroacetate with pig pancreatic lipase.
- 社団法人日本農芸化学会の論文
- 1998-02-23
著者
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Ikeda Hajime
Department Of Chemistry Keio University
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Ohta Hiromichi
Department Of Chemistry Faculty Of Science And Technology Keio University
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SUGAI Takeshi
Department of Chemistry, Faculty of Science and Technology, Keio University
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Ohta Hiromichi
Department Of Chemistry Keio University
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OHBA Shigeru
Department of Chemistry, Keio University
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Ohba Shigeru
Department Of Applied Physics Nagoya University:the Institute For Solid State Physics The University
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Ohta Hiromichi
Department Of Applied Chemistry School Of Engineering Nagoya University
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HOSOMI Hiroyuki
Department of Chemistry, Keio University
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Sugai Takeshi
Department Of Agricultural Chemistry The University Of Tokyo
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Hosomi H
Keio Univ. Yokohama
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Hosomi Hiroyuki
Department Of Chemistry Faculty Of Science And Technology Keio University
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Ohba S
Department Of Chemistry Keio University
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OHBA SHIGERU
Deparment of Biology, Faculty of Science, Tokyo Metropolitan University
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