Stereoselective Synthesis of (1S,3R-1-Aminocyclopentane-1,3-dicarboxylic Acid via C-H Insertion of Alkylidenecarbene(Organic Chemistry)
スポンサーリンク
概要
- 論文の詳細を見る
(1S,3R)-1-Aminocyclopentane-1,3-dicarboxylic acid (ACPD), a potent agonist of metabotropic glutamate receptors, was synthesized from L-serine. The chiral quaternary center was constructed by C-H insertion of the alkylidenecarbene, this being generated by the reaction between lithiotrimethylsilyldiazomethane and the corresponding ketone.
- 社団法人日本農芸化学会の論文
- 2002-04-23
著者
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KUBOKI Atsuhito
Department of Chemistry, Keio University
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OHIRA Susumu
Department of Biological Chemistry, Faculty of Science, Okayama University of Science
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Ohira S
Department Of Biological Chemistry Faculty Of Science Okayama University Of Science
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Ohira Susumu
Department Of Biochemistry Okayama University Of Science
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Kuboki Atsuhito
Department Of Biological Chemistry Faculty Of Science Okayama University Of Science
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Kuboki Atsuhito
Department Of Biochemistry Okayama University Of Science
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AKIYAMA Megumi
Department of Biological Chemistry, Faculty of Science, Okayama University of Science
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KAMIHARA Kumiko
Department of Biological Chemistry, Faculty of Science, Okayama University of Science
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ISODA Yuichi
Department of Biological Chemistry, Faculty of Science, Okayama University of Science
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Isoda Yuichi
Department Of Biological Chemistry Faculty Of Science Okayama University Of Science
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Akiyama Megumi
Department Of Biological Chemistry Faculty Of Science Okayama University Of Science
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Kamihara Kumiko
Department Of Biological Chemistry Faculty Of Science Okayama University Of Science
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