Microbial Oxidation of Cyclic Alcohols to the Corresponding Ketones
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概要
- 論文の詳細を見る
Corynebacterium equi IFO 3730, which had been shown to have an enzyme system for oxidizing a wide variety of linear secondary alcohols, gave the corresponding ketones on incubation with cycloalkanols. The bacterium showed an interesting substrate specificity, i.e., although cyclohexanol and cyclododecanol were oxidized smoothly, a large portion of cyclooctanol was recovered unaffected under the same conditions. The stereochemistry of the substrates had a marked effect on this microbial transformation, cis and trans-4-tert-Butylcyclohexanol showed a remarkable contrast, in that the former was oxidized smoothly by C. equi but the latter was little affected.
- 社団法人 日本農芸化学会の論文
著者
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Fujiwara Hidenori
Department Of Bioresources Science Graduate School Of Science And Technology Chiba University
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Ohta Hiromichi
Department Of Applied Chemistry School Of Engineering Nagoya University
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Tsuchihashi Gen-ichi
Department Of Chemistry Faculty Of Science And Technology Keio University
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TSUCHIHASHI Gen-ichi
Department of Chemistry, Faculty of Science and Technology, Keio University
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