The synthesis and electrical resistivities of complexes of cation-TCNQ-salts with crown ethers, cryptands, and 1,13-di(8-quinolyl)-1,4,7,10,13-pentaoxatridecane.
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概要
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Cation–TCNQ complexes with crown ethers, cryptands, and 1,13-di(8-quinolyl)-1,4,7,10,13-pentaoxatridecane were isolated. The cations include alkali-metal, and alkyl- and arylammonium ions. Nine types of complexes were isolated. These complexes are classified into two groups: complexes containing neutral TCNQ, and the complexes not containing neutral TCNQ. The electrical resistivities of the compaction samples were mainly measured at room temperature. The complexes containing neutral TCNQ were much more conductive than the other type of complexes; they exhibit resistivities of 8.2–10<SUP>3</SUP> Ω cm. The complexes of 1,13-di(8-quinolyl)-1,4,7,10,13-pentaoxatridecane contained methanol when we synthesized them from methanol solution.
- 公益社団法人 日本化学会の論文
著者
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Tanaka Hidekazu
Department Of Chemistry And Chemical Biology Gunma University
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Mikawa Hiroshi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Nogami Takashi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Matsuoka Katsumi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Matsumoto Tsuruyoshi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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