Aerobic Oxidation of Olefins to Epoxides Using a Copper(II)-Aldehyde System
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概要
- 論文の詳細を見る
Epoxidation of olefins was successfully achieved using molecular oxygen in the presence of an aldehyde and a catalytic amount of CuCl2 at room temperature. Hexanal was found to be a particularly good reducing agent for the CuCl2-catalyzed epoxidation. A good correlation was observed between the reactivity and the calculated ionization potential for some of the aldehydes tested. The present system was applied to epoxidation of a range of olefins in high to excellent yields.
- 日本油化学会の論文
- 2002-08-01
著者
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Komatsu M
Osaka Univ. Osaka
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Komatsu Mitsuo
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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Komatsu Mitsuo
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Komatsu M
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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MINAKATA Satoshi
Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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INAKI Kanako
Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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Inaki Kanako
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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Minakata S
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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Minakata Satoshi
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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