Formation Mechanism of 2, 6-Dimethyl-2, 6-Octadienes from Thermal Decomposition of Linalyl β-D-Glucopyranoside
スポンサーリンク
概要
- 論文の詳細を見る
Thermally decomposed products of (±)-linalyl β-D-glucoside were analyzed by GC and GC/MS. 2,6-Dimethyl-2,6-octadienes produced by mild pyrolysis of linalyl β-D-glucopyranoside under a vacuum were detected and characterized by MS and NMR spectroscopy. This suggests that 2,6-dimethyl-2,6-octadienes are produced during thermal decomposition of the glucoside via proton transfer from the anomeric position to C-6 in the aglycon moiety. A stable isotope labeling experiment directly indicated the new reaction mechanism.
- 社団法人 日本農芸化学会の論文
- 2004-12-23
著者
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Tazaki Hiroyuki
Department of Veterinary and Animal Science ,Nippon Veterinary and Life Science University
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NABETA Kensuke
Department of Bioresource Science, Obihiro University of Agriculture and Veterinary Medicine
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Kimura Koji
Department of Cardiovascular Surgery, Medicine, Radiology, and Pathology, National Cardiovascular Ce
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Ohnishi Masao
Department of Food Science, Obihiro University of Agriculture and Veterinary Medicine
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Ohnishi Masao
Department Of Bioresource Science Obihiro University Of Agriculture And Veterinary Medicine
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Nabeta Kensuke
Department Of Agricultural Chemistry Obihiro University Of Agriculture And Veterinary Medicine
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Ohnishi Masao
Department Of Agricultural And Life Science Obihiro University Of Agriculture And Veterinary Medicin
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Fujimori Takane
Soda Aromatic Co. Ltd. Analysis Research Department
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Tazaki Hiroyuki
Department Of Bioresource Chemistry Obihiro University Of Agriculture And Veterinary Medicine
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HATTORI Shoji
Soda Aromatic Co., Ltd., Analysis Research Department
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KAWAHARADA Chiami
Department of Bioresource Science, Obihiro University of Agriculture and Veterinary Medicine
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Hattori Shoji
Soda Aromatic Co. Ltd. Analysis Research Department
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Hattori Shoji
Soda Aromatic Co. Ltd.
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Kawaharada Chiami
Department Of Bioresource Science Obihiro University Of Agriculture And Veterinary Medicine
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Kimura Koji
Department Of Bioresource Science Obihiro University Of Agriculture And Veterinary Medicine
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Kimura Koji
Department Of Animal Breeding And Reproduction National Institute Of Livestock And Grassland Science
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TAZAKI Hiroyuki
Department of Agricultural Chemistry, Faculty of Agriculture, Hokkaido University
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