Nine New Triterpene Saponins, Polygalasaponins XXXIII-XLI from the Roots of Polygala fallax HEMSL.

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概要

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• Nine new oleanate-type saponins, polygalasaponins XXXIII-XLI, along with seven known saponins were isolated from the roots of Polygala fallax HEMSL. Polygalasaponins XXXIII-XLI were elucidated as 3-O-β-D-glucopyranosyl presenegenin 28-O-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-(4-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-(4-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-(3,4-di-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-[(5-O-acetyl)-β-D-apiofuranosyl-(1→3)]-α-L-rhamnopyranosyl-(1→2)-(3,4-di-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl presenegenin 28-O-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-(3-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-(4-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl presenegenin 28-O-β-D-xylopyranosyl-(1→4)-α-L-rhamnopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→3)]-(4-O-acetyl)-β-D-fucopyranosyl ester, 3-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-[β-D-apiofuranosyl-(1→3)]-α-L-rhamnopyranosyl-(1→2)-(3,4-di-O-acetyl)-β-D-fucopyranosyl ester and 3-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl presenegenin 28-O-β-D-galactopyranosyl-(1→4)-β-D-xylopyranosyl-(1→4)-[(5-O-acetyl)-β-D-apiofuranosyl-(1→3)]-α-L-rhamnopyranosyl-(1→2)-(3,4-di-O-acetyl)-β-D-fucopyranosyl ester, respectively, on the basis of spectroscopic and chemical evidence.

• 公益社団法人日本薬学会の論文
• 1996-11-15

著者

• UMEHARA Kaoru

  School of Pharmaceutical Sciences, University of Shizuoka

• KUROYANAGI Masanori

  School of Bioresources, Hiroshioma Prefectural University

• MIYASE Toshio

  School of Pharmaceutical Sciences, University of Shizuoka

• Kuroyanagi M

  Fac. Of Pharmaceutical Sciences At Kagawa Campus Tokushima Bunri Univ.

• Miyase T

  School Of Pharmaceutical Sciences University Of Shizuoka

• Miyase Toshio

  School Of Pharmaceutical Science University Of Shizuoka

• 梅原 薫

  School of Pharmaceutical Sciences, University of Shizuoka

• Noguchi Hiroshi

  School of Pharmaceutical Sciences and the COE 21 Program, University of Shizuoka

• Umehara K

  School Of Pharmaceutical Sciences University Of Shizuoka

• 梅原 薫

  School Of Pharmaceutical Sciences University Of Shizuoka

• ZHANG Dongming

  School of Pharmaceutical Sciences, University of Shizuoka

• Umehara Kaoru

  School Of Pharmaceutical Sciences University Of Shizuoka

• Kuroyanagi M

  Department Of Life Sciences Faculty Of Life And Environmental Science Prefectural University Of Hiro

• Kuroyanagi Masanori

  School Of Bioresources Hiroshima Prefectural University

• Zhang Dongming

  Key Laboratory Of Atomic And Molecular Nanosciences Of Education Ministry Department Of Physics Tsin

• Zhang Dongming

  School Of Pharmaceutical Sciences University Of Shizuoka

• Noguchi H

  Department Of Biology Faculty Of Science Chiba University

• Noguchi Hiroshi

  School Of Pharmaceutical Sciences And The Coe 21 Program University Of Shizuoka

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