Construction of Asymmetric Quaternary Carbon Center Containing Heteroatom via Regioselective Cleavage of Cyclopropane Ring Mediated by Mercury(II) Salt

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概要

• 論文の詳細を見る

• (6S, 7S)-1-Oxa-7-bromomethylspiro[5.5]undecanes (12 and 13) were synthesized from the optically active alkenyl sulfoxide (7). The key step involves a tandem regioselective cleavage of cyclopropane ring and stereoselective nucleophilic cyclization of the cyclopropylcarboxylic acid (11).

• 社団法人日本薬学会の論文
• 1993-11-15

著者

• 竹本 佳司

  Faculty Of Pharmaceutical Sciences Osaka University

• 田中 徹明

  Faculty of Pharmaceutical Sciences, Osaka University

• 岩田 宙造

  Faculty of Pharmaceutical Sciences, Osaka University

• 前崎 直容

  Faculty of Pharmaceutical Sciences, Osaka University

• 岩田 宙造

  阪大院薬

• 前崎 直容

  阪大院薬

• 田中 徹明

  阪大院薬

• 田中 徹明

  Faculty Of Pharmaceutical Sciences Osaka University

• 竹内 淳

  Faculty Of Pharmaceutical Sciences Osaka University

• Tanaka T

  Kvushu Univ. Fukuoka Jpn

• 邑楽 泰一

  Faculty of Pharmaceutical Sciences, Osaka University

• Tanaka T

  Osaka Univ. Osaka Jpn

• Takemoto Yoshiji

  Faculty Of Pharmaceutical Sciences Osaka University

• Takemoto Y

  Graduate School Of Pharmaceutical Sciences Kyoto University

• 岩田 宙造

  Faculty Of Pharmaceutical Sciences Osaka University

• Tanaka Tetsuaki

  Faculty Of Pharmaceutical Sciences Osaka University

• Ohra T

  Faculty Of Pharmaceutical Sciences Osaka University

• 邑楽 泰一

  Faculty Of Pharmaceutical Sciences Osaka University

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