Synthetic Studies on Aromadendrane-Type Compounds. II.Stereoselective Synthesis of (+)-1,2-Didehydroaromadendrane

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概要

• 論文の詳細を見る

• The reactivity of the tricyclic enone, (+)-(1S, 2R, 4R, 7R)-3,3,7-trimethyltricyclo[6.3.0.0^<2,4>]undec-8-en-10-one(1), obtained previously as the key intermediate for the synthesis of compounds bearing the aromadendrane uncleus was investigated, and a natural aromadendrane-type sesquiterpene, (+)-1,2-didehydroaromadendrane (2), was synthesized via regio- and stereo-specific introduction of a methyl group at the C-11 position of 1 followed by reductive deoxygenation.

• 社団法人日本薬学会の論文
• 1994-06-15

著者

• 田中 徹明

  Faculty of Pharmaceutical Sciences, Osaka University

• 岩田 宙造

  Faculty of Pharmaceutical Sciences, Osaka University

• 岩田 宙造

  阪大院薬

• 田中 徹明

  阪大院薬

• 田中 徹明

  Faculty Of Pharmaceutical Sciences Osaka University

• Tanaka T

  Kvushu Univ. Fukuoka Jpn

• 三神山 秀勲

  阪大薬

• 前田 公也

  阪大薬

• 三神山 秀勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 船越 洋祐

  Faculty of Pharmaceutical Sciences, Osaka University

• 上中 健司

  Faculty of Pharmaceutical Sciences, Osaka University

• 前田 公也

  Faculty of Pharmaceutical Sciences, Osaka University

• Tanaka T

  Osaka Univ. Osaka Jpn

• 岩田 宙造

  Faculty Of Pharmaceutical Sciences Osaka University

• 田中 恒雄

  Department Of Pharmacy Hyogo College Of Medicine

• Tanaka Tetsuaki

  Faculty Of Pharmaceutical Sciences Osaka University

• 上中 健司

  Faculty Of Pharmaceutical Sciences Osaka University

• 船越 洋祐

  Faculty Of Pharmaceutical Sciences Osaka University

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