Carbon-13 Nuclear Magnetic Resonance Study of meso-Hexestrol and Its Derivatives
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概要
- 論文の詳細を見る
The carbon-13 unclear magnetic resonance chemical shift assignments for meso-hexestrol (1a), made on the basis of two-dimensional ^<13>-^1H chemical shift correlation, long-range selective ^1H decoupling experiment, and a reported two-dimensional Fourier-trasform experiment for long-range proton-carbon-13 spin coupling constants, are reported. For measurement of carbon-protoncoupling constants of meso-hyxestrol derivatives (1b-e, 2a-d, 3a-c, and 4), the coupling informaiton was detected by using a gated decoupling facility which permitted retention of the nuclear Overhauser enhancement and a long-range selective ^1H decoupling experiment. The results showed that the aromatic carbon resonances are influenced by the structure (no double bond, or one or two double bond(s)) of the hexane framework in the central portion.
- 公益社団法人日本薬学会の論文
- 1988-04-25
著者
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佐藤 良博
共立薬科大学名誉
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小田 泰子
Kyoritsu College of Pharmacy
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佐藤 良博
Kyoritsu College of Pharmacy
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佐藤 良博
共立薬大
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村井 知子
Kyoritsu College Of Pharmacy
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