Organic Phosphates. XIV. Reaction of Catechol Cyclic Phosphate with Monoacetoneglucose ; A Novel Synthesis of D-Glucose 6-Phosphate.

スポンサーリンク

概要

• 論文の詳細を見る

• The alcoholysis of catechol cyclic phosphate with 1,2-o-isopropylidene-D-glucofuranose was examined. A primary alcoholysis product (I) was formed in a good yield and its structure was determined as o-hydroxyphenyl 1,2-o-isopropylidene-D-glucofuranose 6-phosphate. (I) was hydrolyzed with acid or alkali into two isomeric monoacetoneglucose mono-phosphates which were identified with 1,2-o-isopropylidene-D-glucofuranose 5-phosphate (II) and 6-phosphate (III'). On further acid hydrolysis, (II) gave a mixture of D-gluco-furanose 5-phosphate (IV) and D-glucopyranose 6-phosphate (V), while (III') only gave (V). The sequences in the hydrolysis reaction of (I) to produce these several products and the availability of this alcoholysis reaction for the preparation of D-glucose 6-phosphate were discussed.

• 公益社団法人日本薬学会の論文
• 1961-07-25

著者

• 長沢 金蔵

  School Of Pharmaceutical Sciences Kitasato University

• 浮田 忠之進

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 長沢 金蔵

  Faculty of Pharmaceutical Sciences, Kitasato University

• 浮田 忠之進

  Faculty Of Pharmaceutical Sciences The University Of Tokyo

関連論文

• Modifications of Nucleosides and Nucleotides. II. Reaction of Ethylene Oxide with 1-Methylcytosine
• メチルコバラミン(ビタミンB_アナローグ)による無機水銀の化学的メチル化反応
• 水銀の迅速定量分析法に関する研究
• On the Benzylation of Nucleosides. II. A Novel Synthesis of 2'-O-Benzyluridine
• On the Benzylation of Nucleosides. I. Reaction of Uridine with Benzyl Bromide in the Presence of Sodium Hydride
• Organic Phosphates. XIX. A Novel Phosphorylation of Nucleosides and Related Compounds with Hydrobenzoin Cyclic Phosphate activated by Diphenyl Phosphorochloridate.
• Syntheses of Unnatural Pyrimidine Nucleosides
• アルカリ分解成績体の検出による有機リン酸系殺虫剤の同定について
• Organic Phosphates. XI. Syntheses of Several 2', 3'-Cyclic Ribonucleotides and their Properties as Substrate for Ribonuclease.
• Organic Phosphates. X. Several 2,3-Cyclic Phosphates of D-Ribofuranoside and their Properties as Substrate for Ribonuclease.
• Organic Phosphates. IX. An Effective Separation of Flavin Nucleotides and Adenine Nucleotide from Hydrolysates of Flavin Adenine Dinucleotide
• Syntheses of 2,3-Cyclie Ribonucleotides and their Properties as Substrate of Ribonuclease
• Several 2,3-Cyclic Phosphates of D-Ribofuranoside and their Properties as Substrate of Ribonuclease
• Organic Phosphates. IV. Synthesis of Several Bis (2-hydroxyalkyl) and Methyl 2-Hydroxyalkyl Phosphates.
• Organic Phosphates. III. Studies on Alcoholysis of Several Cyclic Phosphates.
• Organic Phosphates. II. Studies on Hydrolysis of Several Cyclic Phosphates.
• Organic Phosphates. I. Synthesis of 1,2-Diol Cyclic Phosphates.
• 局所麻酔薬の微量分析法(第4報) : 脳脊髄液中ジブカインの螢光分析法
• 酸素ボンブ燃焼法による水銀の微量定量法
• アルドリンの光分解
• 毛髪中水銀化合物の酸抽出法による定性定量法
• 局所麻酔剤の微量分析法(III) : 脳脊髄液中の局所麻酔剤の分析法について
• ガスクロマトグラフィーによる酸化防止剤の分析
• On the Synthesis of Uridylyl-(3'→5')-uridine
• Syntheses of 1-(5'-Amino-5'-deoxy-β-D-xylofuranosyl) uracil and Its N_3-Methyl Derivative
• The Syntheses of Glycosylbarbiturate.
• Synthesis of 1-(β-D-Ribofuranosyl) urea and Related Compounds.
• 局所麻酔剤の微量分析法(I) : ガスクロマトグラフィーによる分離
• Organic Phosphates. XIII. Studies on Alkaline Hydrolysis of Cyclic Phosphotriesters.
• Organic Phosphates. XII. Hydrobenzoin Cyclic Phosphoro-chloriodate as a Phosphorylating Agent.
• Studies on Azulenes. VI. Synthesis of Azulenes from Hydrindeneglycol Diacetate without Dehydrogenation.
• Studies on Azulenes. V. S-Guaiazulene-3-sulfonic Acid.
• アズレン類の研究(第2報)ポリブロムアズレン類の合成
• Reactions of Methyl Iodide on 2,2'-Anhydro-1-(β-D-arabinofuranosyl)-uracil and 2,3'-Anhydro-1-(β-D-xylofuranosyl) uracil
• Reaction of Hydrogen Halides on 2,3'-Anhydro-1-(β-D-xylofuranosyl) uracil
• Studies on Azulenes. IX. 3-(1-Hydroxyethyl)-S-guaiazulene.
• Studies on Azulenes : S-Guaiazulene-aldehydes
• Synthesis of 2'-Deoxy-2'-thio-3'-deoxy-3'-aminouridine.
• Some Attempts on Substitution of 2'-Position of Uridine with Thiol Group.
• Synthesis of 2'-Deoxy-2'-thio-3'-deoxy-3'-aminouridine
• Reaction of Sodium Hypochlorite with Nucleic Acids and Their Constituents
• β-ベンゾイルアクリル酸エチルとリボヌクレオチド類の反応について
• Modifications of Nucleosides and Nucleotides. I. Reaction of Ethylene Oxide with Uridine and Uridylic Acid.
• A Reinvestigation of the Condensation Reaction of Acetobromoglucose with Chloromercuri-4-ethoxy-2 (1H) -pyrimidinone to 1-(Tetra-O-acetyl-β-D-glucopyranosyl)-4-ethoxy-2 (1H)-pyrimidinone.
• Organic Phosphates. XVIII. Syntheses of Lyxouridine 2', 3'-Cyclic Phosphate and Related Compounds.
• In vitro Screening of Tricarbonylmethane and Related Compounds for their Anti-tumor Effect by Cylinder Agar Plate (CAP) Method.
• Synthesis of 1,2-Naphthoquinone 1-Oxime O-Sulfate and Its Solvolytic Properties with or without Bivalent Copper
• Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc
• Preparation of Phosphate and Pyrophosphate Esters by the Metal-catalyzed Reaction of 8-Quinolyl Phosphates
• Synthesis and Characterization of Chinoform Sulfate
• A Metal Catalyzed Phosphorylation with 8-Quinolyl Phosphates
• Reaction between Carbohydrates and Sulfuric Acid. III. Depolymerization and Sulfation of Chitosan by Sulfuric Acid
• Reaction between Carbohydrates and Sulfuric Acid. (2). Depolymerization and Sulfation of Chondroitin Sulfate by Sulfuric Acid
• Reaction between Riboflavin and Sulfuric Acid : Formation and Characterization of Riboflavin Polysulfates
• Alcoholysis Reaction of Sulfamic Acids and Its Application to the Preparation of biochemically Related Sulfate Esters
• Solvent Catalytic Degradation of Sulfamic Acid and Its N-Substituted Derivatives
• The Preparation of Acylated Derivatives of 2-Amino-6-purinethiol and Related Compounds
• 合成甘味料サイクラミン酸の新定量法
• Organic Phosphates. XIV. Reaction of Catechol Cyclic Phosphate with Monoacetoneglucose ; A Novel Synthesis of D-Glucose 6-Phosphate.
• Synthesis of 2-Deoxy-D-ribose 5-Phosphate
• Organic Phosphates. VIII. A Novel Synthesis of Riboflavin 5'-Phosphate.
• Organic Phosphates. VII. Alcoholyses of Catechol Cyclic Phosphate. (2).
• Organic Phosphates. VI. Alcoholysis of Catechol Cyclic Phosphates. (1).
• A Novel Synthesis of DL-Glyceraldehyde 3-Phosphate.
• 放射化分析による毛髪中水銀の定量
• ブロムワレリル尿素製剤のガスクロマトグラフィーによる分析
• 局所麻酔剤の微量分析法(II) : 薄層および前処理ろ紙クロマトグラフィーによる定性
• 生体試料中のエーテルの微量分析法
• 健康人毛髪中の水銀量の居住環境による差異について
• 有機水銀中毒時の尿, 血液, 毛髪中の水銀量について
• 大豆油に添加したBHTの紫外線による分解について
• 生体試料中のTrichloroethyl Phosphateの微量分析
• On the Anti-tumor Activity of Nitrogenous Cyclic β-Diketones.
• サイクラミン酸のトリフルオロアセトリシスとガスクロマトグラフィーによるサイクラミン酸の微量定量法
• Organic Phosphates. XX. Syntheses of 1-(3-Cyanoethylphosphoryl-5-trityl-D-ribofuranosyl)-2(1H)-pyrimidinone, -6(1H)-pyrimidinone, and -2(1H)-pyridone and their Properties as Substrate of Bovine Pancreatic Ribonuclease
• 〔2〕裁判化学上の問題について(殺虫剤による危害とその防止, 特に有機リン製剤について)
• サントニン類似体の研究(第4報) : ジヒドロアラントラクトンの還元により得られたイソテトラヒドロアラントラクトンについて
• サントニン類似体の研究(第3報) : ジヒドロアラントラクトンより得られたモノカルボン酸について
• Fluorescence Characteristics of Benzidine and Its Application to Determination of Microgram Quantities of Nitrite
• Fluorometric Method for Determination of Mercury (II) with Rhodamine B
• Studies on the Anti-tumor Component in the Seeds of Coix Lachryma-Jobi L. VAR. Ma-yuen (ROMAN.) STAPF. I. : Isolation and Anti-tumor Activity of Coixenolide.
• Reductive Cleavage of Sulfur Containing Organophosphorus Compounds with Raney Nickel
• 〔VII〕放射化分析による頭髪中水銀の定量(有害性金属について : 第22回日本薬学大会)
• 食品中の残留カルバメート系農薬の薄層クロマトグラフィーによる検出の為のクリーンアップ法
• Reductive Cleavage of Sulfur-containing Carbamates with Raney Nickel
• カーバメイト系殺虫剤の薄層クロマトグラフィー
• Ion-Exchange Chromatography of Amino Acids and Related Amines on Cellulose Sulfate-Impregnated Cellulose Thin-Layers
• Protection of Mammalia from the Poisoning of Radioactive Strontium. IV. Aluminum Citrate
• Antibacterial Activity of Compounds possessing a Tricarbonylmethane Group. XI. Synthesis of a Compound having Structure analogous to A-Ring of Tetracycline.
• Antibacterial Properties of Compounds Containing the Tricarbonylmethane Group. IX. : Effects of Nitrogenous Radicals in the Side-chains of 3-Acyl-4-hydroxycoumarins and its Derivatives.
• Nucleosides and Nucleotides. XII. Synthesis and Properties of 2'-Deoxy-2'-mercaptouridine and Its Derivatives
• Organic Phosphates. XVI. Synthesis and Alcoholysis Reaction of 9,10-Dihydro-9,10-phenanthrenediol Cyclic Phosphate.
• Organic Phosphates. XV. Synthesis and Alcoholysis Reaction of 4,4'-Dinitro-hydrobenzoin Cyclic Phosphate.
• はいびやくしん果実中の樹脂酸の研究・7-Isodextropimaric Acid異性体の構造について
• 放射性ストロンチウムによる体内汚染の防禦に関する研究

もっと見る 閉じる

スポンサーリンク