Alcoholysis Reaction of Sulfamic Acids and Its Application to the Preparation of biochemically Related Sulfate Esters
スポンサーリンク
概要
- 論文の詳細を見る
The alcoholysis reaction of sulfamic acids catalyzed by pyridine was investigated with piperidine-N-sulfonic acid-cyclohexanol system and a possible formation and participation of the intermediate "pyridine-SO_3 adduct" in the reaction was suggested. To apply this reaction to the preparation of sulfate esters, the experimental conditions such as the kind of sulfamic acids, molar ratio of reactants, and temperature and time of reaction were examined. Biochemically related sulfate esters, adenosine 5'-sulfate, riboflavin 5'-sulfate, and D-galactose 6-sulfate, were synthesized by this reaction.
- 公益社団法人日本薬学会の論文
- 1970-10-25
著者
-
長沢 金蔵
School Of Pharmaceutical Sciences Kitasato University
-
長沢 金蔵
Faculty of Pharmaceutical Sciences, Kitasato University
-
吉留 久枝
Faculty of Pharmaceutical Sciences, Kitasato University
-
吉留 久枝
School Of Pharmaceutical Sciences Kitasato University
関連論文
- Organic Phosphates. XIX. A Novel Phosphorylation of Nucleosides and Related Compounds with Hydrobenzoin Cyclic Phosphate activated by Diphenyl Phosphorochloridate.
- Organic Phosphates. IV. Synthesis of Several Bis (2-hydroxyalkyl) and Methyl 2-Hydroxyalkyl Phosphates.
- Synthesis of 1,2-Naphthoquinone 1-Oxime O-Sulfate and Its Solvolytic Properties with or without Bivalent Copper
- Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc
- Preparation of Phosphate and Pyrophosphate Esters by the Metal-catalyzed Reaction of 8-Quinolyl Phosphates
- Synthesis and Characterization of Chinoform Sulfate
- A Metal Catalyzed Phosphorylation with 8-Quinolyl Phosphates
- Reaction between Carbohydrates and Sulfuric Acid. III. Depolymerization and Sulfation of Chitosan by Sulfuric Acid
- Reaction between Carbohydrates and Sulfuric Acid. (2). Depolymerization and Sulfation of Chondroitin Sulfate by Sulfuric Acid
- Reaction between Riboflavin and Sulfuric Acid : Formation and Characterization of Riboflavin Polysulfates
- Alcoholysis Reaction of Sulfamic Acids and Its Application to the Preparation of biochemically Related Sulfate Esters
- Solvent Catalytic Degradation of Sulfamic Acid and Its N-Substituted Derivatives
- The Preparation of Acylated Derivatives of 2-Amino-6-purinethiol and Related Compounds
- 合成甘味料サイクラミン酸の新定量法
- Organic Phosphates. XIV. Reaction of Catechol Cyclic Phosphate with Monoacetoneglucose ; A Novel Synthesis of D-Glucose 6-Phosphate.
- Synthesis of 2-Deoxy-D-ribose 5-Phosphate
- Organic Phosphates. VIII. A Novel Synthesis of Riboflavin 5'-Phosphate.
- Organic Phosphates. VII. Alcoholyses of Catechol Cyclic Phosphate. (2).
- Organic Phosphates. VI. Alcoholysis of Catechol Cyclic Phosphates. (1).
- A Novel Synthesis of DL-Glyceraldehyde 3-Phosphate.
- サイクラミン酸のトリフルオロアセトリシスとガスクロマトグラフィーによるサイクラミン酸の微量定量法
- Fluorescence Characteristics of Benzidine and Its Application to Determination of Microgram Quantities of Nitrite
- Fluorometric Method for Determination of Mercury (II) with Rhodamine B
- Reductive Cleavage of Sulfur Containing Organophosphorus Compounds with Raney Nickel
- 食品中の残留カルバメート系農薬の薄層クロマトグラフィーによる検出の為のクリーンアップ法
- Reductive Cleavage of Sulfur-containing Carbamates with Raney Nickel
- カーバメイト系殺虫剤の薄層クロマトグラフィー
- Ion-Exchange Chromatography of Amino Acids and Related Amines on Cellulose Sulfate-Impregnated Cellulose Thin-Layers