Organic Phosphates. VI. Alcoholysis of Catechol Cyclic Phosphates. (1).
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概要
- 論文の詳細を見る
Catechol cyclic phosphate (CCP) (IV) was found to be alcoholyzed with several primary and secondary monofunctional alcohols to give the corresponding alkyl or aralkyl ohydroxyphenyl phosphate (V) in a yield of 47〜65%. These reactions proceeded by the catalytic function of the acid reagent, CCP, used. The products (V) were further hydrolyzed by acid or alkali to give the corresponding alcohols and o-hydroxyphenyl phosphate. The catechol moiety of (V) was found inert against catalytic hydrogenolysis, while it was hydrolyzed by snake venom phosphodiesterase to alkyl or aralkyl phosphates.
- 公益社団法人日本薬学会の論文
- 1959-06-10
著者
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長沢 金蔵
School Of Pharmaceutical Sciences Kitasato University
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長沢 金蔵
Faculty of Pharmaceutical Sciences, Kitasato University
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