Organic Phosphates. VII. Alcoholyses of Catechol Cyclic Phosphate. (2).
スポンサーリンク
概要
- 論文の詳細を見る
The alcoholysis of catechol cyclic phosphate (I) with several polyols was investigated. Ethylene glycol and 1,2-propanediol gave the corresponding hydroxyalkyl 1,2-cyclic phosphates (III) via intermediate hydroxyalkyl o-hydroxyphenyl phosphates (II). (III) were hydrolyzed by acid to the corresponding hydroxyalkyl phosphates (IV). In the case of the polyols containing more than three vicinal hydroxyl groups such as, glycerol, erythritol, and mannitol, the intermediates (II) were too labile to be detected on paper chromatogram of the reaction products, but converted into the corresponding cyclic phosphates (III) which were further hydrolyzed to (IV). Thus glycerol 1,2-cyclic phosphate, DL-erythritol 1-phosphate, and D-mannitol 1-phosphate were isolated and identified.
- 公益社団法人日本薬学会の論文
- 1959-06-10
著者
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長沢 金蔵
School Of Pharmaceutical Sciences Kitasato University
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浮田 忠之進
Faculty of Pharmaceutical Sciences, University of Tokyo
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長沢 金蔵
Faculty of Pharmaceutical Sciences, Kitasato University
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浮田 忠之進
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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