Organic Phosphates. XV. Synthesis and Alcoholysis Reaction of 4,4'-Dinitro-hydrobenzoin Cyclic Phosphate.
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概要
- 論文の詳細を見る
4,4'-Dinitrohydrobenzoin cyclic phosphate was synthesized. Alcoholysis reaction of this compound with various hydroxylic compounds in acid or alkaline medium was found to occur to a greater extent than a similar reaction for non-substituted hydrobenzoin cyclic phosphates. Thus, the new cyclic phosphate was alcoholyzed with polyols such as DL-erythritol and D-mannitol, which were found to be inert to the non-substituted hydrobenzoin cyclic phosphate. The mode of the hydrolysis reaction of methyl 4,4'-dinitrohydrobenzoin phosphate, an intermediate product of methanolysis of 4,4'-dinitrohydrobenzoin cyclic phosphate, in acid and alkaline media was found to be different from that of methyl hydrobenzoin phosphate.
- 公益社団法人日本薬学会の論文
- 1961-08-25
著者
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竹下 隆三
Department Of Public Health Pharmaceutics The Institute Of Public Health
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浮田 忠之進
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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