Studies on Azulenes. IX. 3-(1-Hydroxyethyl)-S-guaiazulene.
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概要
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3-(1-Hydroxyethyl)-S-guaiazulene (III) was prepared by reduction of 3-acetyl-S-guaiazulene (II) with lithium aluminum hydride. (III) was converted into 3-vinyl-S-guaiazulene (IV) by dehydration and further into 3-ethyl-S-guaiazulene (V) by catalytic hydrogenation. An isomeric carbinol (VIII) was also produced from S-guaiazulene-3-carboxaldehyde (VI) by its treatment with methylmagnesium iodide, and (VIII) was confirmed to be 3-(1-hydroxyethyl-S-guaiazulene by its derivation to (V). The remarkably different stability against dehydration observed between the two isomeric 3-(1-hydroxyethyl)-S-guaiazulenes (III and VIII) is discussed from the structural point of view.
- 公益社団法人日本薬学会の論文
- 1960-02-25
著者
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土師 美恵子
Government Forest Experiment Station University Of Tokyo
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浮田 忠之進
Faculty of Pharmaceutical Sciences, University of Tokyo
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宮崎 信
Government Forest Experiment Station
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浮田 忠之進
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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