はいびやくしん果実中の樹脂酸の研究・7-Isodextropimaric Acid異性体の構造について
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概要
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By successive oxidation with selenium dioxide and sodium dichromate followed by introdution of a hydroxymethylene group, a partial structure -C=C-CH_2-CH_2- was given for a diterpenic acid C_<20>H_<30>O_2 (II) which was isolated from the fruits of Japanese juniper. Further, as the acid (II) gave tetrahydro-7-isodextropimaric acid after consumption of two moles of hydrogen, the structure of (II) was concluded to be represented by △^<13,14>-7-isodextropimaric acid. The structure of a doubly unsaturated compound obtainable from a hydroxymethyl ester (VI), an oxidation product of (V), was proposed to be △^<5,13 : 9,14>-7-isodextropimaric acid.
- 公益社団法人日本薬学会の論文
- 1955-12-20
著者
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浮田 忠之進
Institute for Infectious Diseases, University of Tokyo
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浮田 忠之進
Faculty Of Pharmaceutical Sciences The University Of Tokyo
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宇都木 允之
Institute For Infectious Diseases University Of Tokyo:national Institute Of Health Japan
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積田 亨
Institute for Infectious Diseases, University of Tokyo
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積田 亨
Institute For Infectious Diseases University Of Tokyo:national Institute Of Health Japan
関連論文
- Modifications of Nucleosides and Nucleotides. II. Reaction of Ethylene Oxide with 1-Methylcytosine
- On the Benzylation of Nucleosides. II. A Novel Synthesis of 2'-O-Benzyluridine
- On the Benzylation of Nucleosides. I. Reaction of Uridine with Benzyl Bromide in the Presence of Sodium Hydride
- Organic Phosphates. XIX. A Novel Phosphorylation of Nucleosides and Related Compounds with Hydrobenzoin Cyclic Phosphate activated by Diphenyl Phosphorochloridate.
- Syntheses of Unnatural Pyrimidine Nucleosides
- Organic Phosphates. XI. Syntheses of Several 2', 3'-Cyclic Ribonucleotides and their Properties as Substrate for Ribonuclease.
- Organic Phosphates. X. Several 2,3-Cyclic Phosphates of D-Ribofuranoside and their Properties as Substrate for Ribonuclease.
- Organic Phosphates. IX. An Effective Separation of Flavin Nucleotides and Adenine Nucleotide from Hydrolysates of Flavin Adenine Dinucleotide
- Several 2,3-Cyclic Phosphates of D-Ribofuranoside and their Properties as Substrate of Ribonuclease
- Organic Phosphates. IV. Synthesis of Several Bis (2-hydroxyalkyl) and Methyl 2-Hydroxyalkyl Phosphates.
- Organic Phosphates. III. Studies on Alcoholysis of Several Cyclic Phosphates.
- Organic Phosphates. II. Studies on Hydrolysis of Several Cyclic Phosphates.
- Organic Phosphates. I. Synthesis of 1,2-Diol Cyclic Phosphates.
- On the Synthesis of Uridylyl-(3'→5')-uridine
- Syntheses of 1-(5'-Amino-5'-deoxy-β-D-xylofuranosyl) uracil and Its N_3-Methyl Derivative
- The Syntheses of Glycosylbarbiturate.
- Synthesis of 1-(β-D-Ribofuranosyl) urea and Related Compounds.
- Organic Phosphates. XIII. Studies on Alkaline Hydrolysis of Cyclic Phosphotriesters.
- Organic Phosphates. XII. Hydrobenzoin Cyclic Phosphoro-chloriodate as a Phosphorylating Agent.
- Studies on Azulenes. VI. Synthesis of Azulenes from Hydrindeneglycol Diacetate without Dehydrogenation.
- Studies on Azulenes. V. S-Guaiazulene-3-sulfonic Acid.
- アズレン類の研究(第2報)ポリブロムアズレン類の合成
- Reactions of Methyl Iodide on 2,2'-Anhydro-1-(β-D-arabinofuranosyl)-uracil and 2,3'-Anhydro-1-(β-D-xylofuranosyl) uracil
- Reaction of Hydrogen Halides on 2,3'-Anhydro-1-(β-D-xylofuranosyl) uracil
- Studies on Azulenes. IX. 3-(1-Hydroxyethyl)-S-guaiazulene.
- Studies on Azulenes : S-Guaiazulene-aldehydes
- Synthesis of 2'-Deoxy-2'-thio-3'-deoxy-3'-aminouridine.
- Some Attempts on Substitution of 2'-Position of Uridine with Thiol Group.
- Synthesis of 2'-Deoxy-2'-thio-3'-deoxy-3'-aminouridine
- Reaction of Sodium Hypochlorite with Nucleic Acids and Their Constituents
- Modifications of Nucleosides and Nucleotides. I. Reaction of Ethylene Oxide with Uridine and Uridylic Acid.
- A Reinvestigation of the Condensation Reaction of Acetobromoglucose with Chloromercuri-4-ethoxy-2 (1H) -pyrimidinone to 1-(Tetra-O-acetyl-β-D-glucopyranosyl)-4-ethoxy-2 (1H)-pyrimidinone.
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- In vitro Screening of Tricarbonylmethane and Related Compounds for their Anti-tumor Effect by Cylinder Agar Plate (CAP) Method.
- Organic Phosphates. XIV. Reaction of Catechol Cyclic Phosphate with Monoacetoneglucose ; A Novel Synthesis of D-Glucose 6-Phosphate.
- Synthesis of 2-Deoxy-D-ribose 5-Phosphate
- Organic Phosphates. VIII. A Novel Synthesis of Riboflavin 5'-Phosphate.
- Organic Phosphates. VII. Alcoholyses of Catechol Cyclic Phosphate. (2).
- A Novel Synthesis of DL-Glyceraldehyde 3-Phosphate.
- On the Anti-tumor Activity of Nitrogenous Cyclic β-Diketones.
- Organic Phosphates. XX. Syntheses of 1-(3-Cyanoethylphosphoryl-5-trityl-D-ribofuranosyl)-2(1H)-pyrimidinone, -6(1H)-pyrimidinone, and -2(1H)-pyridone and their Properties as Substrate of Bovine Pancreatic Ribonuclease
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- Studies on the Anti-tumor Component in the Seeds of Coix Lachryma-Jobi L. VAR. Ma-yuen (ROMAN.) STAPF. I. : Isolation and Anti-tumor Activity of Coixenolide.
- Protection of Mammalia from the Poisoning of Radioactive Strontium. IV. Aluminum Citrate
- Antibacterial Activity of Compounds possessing a Tricarbonylmethane Group. XI. Synthesis of a Compound having Structure analogous to A-Ring of Tetracycline.
- Antibacterial Properties of Compounds Containing the Tricarbonylmethane Group. IX. : Effects of Nitrogenous Radicals in the Side-chains of 3-Acyl-4-hydroxycoumarins and its Derivatives.
- Nucleosides and Nucleotides. XII. Synthesis and Properties of 2'-Deoxy-2'-mercaptouridine and Its Derivatives
- Organic Phosphates. XVI. Synthesis and Alcoholysis Reaction of 9,10-Dihydro-9,10-phenanthrenediol Cyclic Phosphate.
- Organic Phosphates. XV. Synthesis and Alcoholysis Reaction of 4,4'-Dinitro-hydrobenzoin Cyclic Phosphate.
- はいびやくしん果実中の樹脂酸の研究・7-Isodextropimaric Acid異性体の構造について