Reductive Cleavage of Sulfur Containing Organophosphorus Compounds with Raney Nickel
スポンサーリンク
概要
- 論文の詳細を見る
The reductive cleavage of sulfur containing organophosphorus compounds and its application to the analysis of organophosphorus pesticides were examined. Cidial, malathion, and dimethoate having a common structure (CH_3O)_2P(S)SR were treated by Raney nickel in ethanol. The non-phosphorus products characteristic to each of the original pesticides were formed, and they were identified with ethyl phenylacetate, diethyl succinate, and N-methylacetamide, respectively. Px which is a main phosphorus containing product common to these pesticides was identified with the phosphorus compound obtained by the same treatment of dimethyl dithiophosphate. The structure of Px and the reaction mechanism were discussed. It was also proved that this reaction afforded a new method to characterize this type of organophosphorus pesticides.
- 公益社団法人日本薬学会の論文
- 1971-11-25
著者
-
長沢 金蔵
School Of Pharmaceutical Sciences Kitasato University
-
山田 利治
School Of Pharmaceutical Sciences Kitasato University
-
小鴨 晃
School Of Pharmaceutical Sciences Kitasato University
関連論文
- Organic Phosphates. XIX. A Novel Phosphorylation of Nucleosides and Related Compounds with Hydrobenzoin Cyclic Phosphate activated by Diphenyl Phosphorochloridate.
- Organic Phosphates. IV. Synthesis of Several Bis (2-hydroxyalkyl) and Methyl 2-Hydroxyalkyl Phosphates.
- Synthesis of 1,2-Naphthoquinone 1-Oxime O-Sulfate and Its Solvolytic Properties with or without Bivalent Copper
- Fluorescence Characteristics of 8-O-Phosphoryl, -Sulfuryl, and -Carboxymethyl Derivatives of 8-Hydroxyquinoline and Its Application to Micro-determination of Cadmium and Zinc
- Preparation of Phosphate and Pyrophosphate Esters by the Metal-catalyzed Reaction of 8-Quinolyl Phosphates
- Synthesis and Characterization of Chinoform Sulfate
- A Metal Catalyzed Phosphorylation with 8-Quinolyl Phosphates
- Reaction between Carbohydrates and Sulfuric Acid. III. Depolymerization and Sulfation of Chitosan by Sulfuric Acid
- Reaction between Carbohydrates and Sulfuric Acid. (2). Depolymerization and Sulfation of Chondroitin Sulfate by Sulfuric Acid
- Reaction between Riboflavin and Sulfuric Acid : Formation and Characterization of Riboflavin Polysulfates
- Alcoholysis Reaction of Sulfamic Acids and Its Application to the Preparation of biochemically Related Sulfate Esters
- Solvent Catalytic Degradation of Sulfamic Acid and Its N-Substituted Derivatives
- The Preparation of Acylated Derivatives of 2-Amino-6-purinethiol and Related Compounds
- 合成甘味料サイクラミン酸の新定量法
- Organic Phosphates. XIV. Reaction of Catechol Cyclic Phosphate with Monoacetoneglucose ; A Novel Synthesis of D-Glucose 6-Phosphate.
- Synthesis of 2-Deoxy-D-ribose 5-Phosphate
- Organic Phosphates. VIII. A Novel Synthesis of Riboflavin 5'-Phosphate.
- Organic Phosphates. VII. Alcoholyses of Catechol Cyclic Phosphate. (2).
- Organic Phosphates. VI. Alcoholysis of Catechol Cyclic Phosphates. (1).
- A Novel Synthesis of DL-Glyceraldehyde 3-Phosphate.
- サイクラミン酸のトリフルオロアセトリシスとガスクロマトグラフィーによるサイクラミン酸の微量定量法
- Fluorescence Characteristics of Benzidine and Its Application to Determination of Microgram Quantities of Nitrite
- Reductive Cleavage of Sulfur Containing Organophosphorus Compounds with Raney Nickel
- 食品中の残留カルバメート系農薬の薄層クロマトグラフィーによる検出の為のクリーンアップ法
- Reductive Cleavage of Sulfur-containing Carbamates with Raney Nickel
- カーバメイト系殺虫剤の薄層クロマトグラフィー
- Ion-Exchange Chromatography of Amino Acids and Related Amines on Cellulose Sulfate-Impregnated Cellulose Thin-Layers