Glycosyl 2-Pyridinecarboxylate as an Effective Glycosyl Donor : Glycosidation of Mannose, 2-Azidosugar, and 2-Deoxysugar into Disaccharides
スポンサーリンク
概要
- 論文の詳細を見る
Glycosylation reactions using a glycosyl 2-pyridinecarboxylate as a glycosyl donor were performed. Glycosyl 2-pyridinecarboxylate was designed based on a variation of the Remote Activation Concept and is activated through bidentate coordination to mild Lewis acids such as copper triflate and tin triflate. This method was effective for the glycosidation of not only glucose, but several other sugars such as the mannose-type, 2-azidosugar-type, and 2-deoxysugar-type. Various disaccharides were obtained in excellent yield by this reaction.
- 1998-08-15
著者
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Kobayashi S
Eisai Research Institute Of Boston Inc.
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KOBAYASHI Susumu
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Furukawa H
Faculty Of Pharmacy Meijo University
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Kobayashi Shoichi
Laboratory Of Food And Health Science Department Of Agro-bioscience Faculty Of Agriculture Iwate Uni
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Kobayashi Susumu
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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Kobayashi Shigeki
Department Of Analytical Chemistry Of Medicines Showa Phamaceutical University
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TAKAO Ken-ichi
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Kobayashi Shigeki
Department Of Analytical Chemistry Of Medicines Showa Pharmaceutical University
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Kobayashi Shigeki
Div. Of Analytical Chemistry Of Medicines Showa Pharmaceutical Univ.
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FURUKAWA Hironori
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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KOIDE Kazunori
Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Takao K
Faculty Of Pharmaceutical Sciences Science University Of Tokyo:(present Address)keio University
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Koide Kazunori
Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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