Kβ X-Ray Emission Spectra and Chemical Environments of Phosphorus in Some Selected Compounds

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概要

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• The phosphorus K f3 emission fluorescence spectra from 10 selected compounds are rnea-svrred with a high-resolution two-crystal vacuum spectrometer. The phosphorus compoundsstudied include inorganic cornpounds K2HPO3, NQH2PO2-H20, N2LH2P03?2.5H20, CazPzO7,Cu3PzO7 and (NaPO3)?; and organic compotrnds tri-c>-tolylphosphine (0-CH3C6H4)3P, tri-m-tolylphosphine (m-CH3C5H.j)3P, tri-p-tolylphosphine (P-CH3C6H4)3P and triphenylphosphineoxide (C(5H5)3PO. The measured P Kf3 emission spectra are discussed in relation to chemicalenvironments arottnd phosphorus atom in the conapounds. It is shown that the P K p emissionspectra are strongly influenced by chemical environments. The effect of o-, m- and p-methylsubstittrtion at the benzene ring (position isomerism) is observed in the emission spectra oftri-o-tolylphosphine, tri-m-tolylphosphine and tri-p-tolylphosphine.

• 社団法人日本物理学会の論文
• 1996-09-15

著者

• SUGIURA Chikara

  Department of Physics, Miyagi University of Education

• Sugiura Chikara

  Depatment Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University

• Sugiura Chikara

  Department Of Applied Physics Faculty Of Engineering

• MURAMATSU Shinji

  Department of Electronic Engineering, Faculty of Engineering, Utsunomiya University

• Sugiura C

  Depatment Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University

• YORIKAWA Hiroharu

  Depatment of Electrical and Electronic Engineering,Faculty of Engineering,Utsunomiya University

• MURAMATSU Shinji

  Depatment of Electrical and Electronic Engineering,Faculty of Engineering,Utsunomiya University

• YORIKAWA Hiroharu

  Department of Electrical and Electronic Engineering,Faculty of Engineering,Utsunomiya University

• Muramatsu S

  Utsunomiya Univ. Utsunomiya

• Muramatsu Shinji

  Department Of Electrical And Electronic Engineering Utsunomiya University

• Yorikawa H

  Depatment Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University

• Yorikawa Hiroharu

  Department Of Electrical And Electronic Engineering Utsunomiya University

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