Kβ X-Ray Emission and K X-Ray Absorption Spectra of Sulfur in Sulfate Compounds
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概要
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With a two-crystal vacuum spectrometer, the sulfur Kβ emission spectra in fluorescence are measured for a series of alkali, alkaline-earth and hydrated 3d transition-metal salts with the SO^<2->_1 ion. In addition, the sulfur K absorption spectra in a series of hydrated 3d transition-metal sulfates are measured with a bent-quartz-crystal vacuum spectrograph. The measured Kβ emission and K absorption spectra are presented along with the sulfur K absorption spectra of alkali and alkaline-earth sulfates reported previously. It is shown that the Kβ emission and K absorption spectra of sulfur in alkali and alkaline-earth sulfates are influenced by the cations, while those of hydrated 3d transition-metal sulfates are little affected by the metal ions. The sulfur Kβ emission spectra and the sulfur K absorption spectra are interpreted in terms of the molecular orbitals of the SO^<2->_4 ion.
- 社団法人応用物理学会の論文
- 1993-08-15
著者
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SUGIURA Chikara
Department of Physics, Miyagi University of Education
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Sugiura Chikara
Department Of Applied Physics Faculty Of Engineering
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