Phosphorus Kβ X-Ray Emission Spectra and Valence-Band Structures of Transition-Metal Phosphides and GaAs_<1-x>P_x
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概要
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The P Kp emission spectra in fltzorescence frona ZrP, NbP, IN/IoP, HIP, TaP, WP, AgPz, CdP3,Mn3Pz, Cd3P3 and GaAs) .P. for 0.2< x< l are measured with a high-resolution two-crystalV2tCL1U1IIl spectrometer equipped with Ge(111) crystals. The influence of unetal atoms appearsdistinctly in the P K f3 emission spectra of transition-metal phosphides. The effect of arsenicatoms appears slightly in the P Kp etaaission spectra of G2LAS1 .P.. The P Kp emission spectraof AgPz, CdP3, Cd3P3 and G.lASO.6 Pg.,j are compared with available P Lz,3 emission and XPSvalence-band spectra on a counn?on energy scale. It is shown that the P 3p electrons interactfairly xvith the metal d electrons in the trpper part of the valence band for .l1#P (M = Zr, Nb,Mo, Hf, Ta, W) and lVII13P2; considerable p-cl, s mixing occurs in the middle part for AgP3 and111 the lower part for CdP3 and Cd3Pz; and the Ga 3d states mix fairly with the P 38 states inGaAs0.5Pg..j.
- 社団法人日本物理学会の論文
- 1996-07-15
著者
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SUGIURA Chikara
Department of Physics, Miyagi University of Education
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Sugiura Chikara
Department Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University
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Sugiura Chikara
Department Of Applied Physics Faculty Of Engineering
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