Kβ X-Ray Emission Spectra and Chemical Environments of Phosphorus and Sulfur in Various Compounds

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概要

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• The P Kβ emission and S Kβ emission spectra in fluorescence from many selected compounds, P_4O_<10>, KPF_6, M_4P_2O_7, M_2SO_3, M_2SO_4, MHSO_4 (M=Na and K), P_4S_n (n=3, 5, 7 and 10), Na_2S_2O_n (n=3-7) and K_2S_2O_n (n=3, 5, 7 and 8), are measured with a high-resolution two-crystal vacuum spectrometer equipped with Ge(111) crystals. The measured Kβ emission spectra are discussed in relation to the fundamental structures of the compounds and interpreted in terms of available molecular-orbital calculations of the PF^-_6 ion and sulfur oxo anions. It is shown that the emission spectra are strongly influenced by chemical environments around phosphorus and sulfur atoms in the compounds, but little affected by the metal ions Na^+ and K^+.

• 社団法人日本物理学会の論文
• 1995-10-15

著者

• Sugiura Chikara

  Department Of Applied Physics Faculty Of Engineering

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• Soft X-Ray Spectra of Lead Sulfide
• Soft X-Ray Spectra of Sulfur in Cubic CdS
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• Chlorine-Kβ X-Ray Emission Band and Valence-Band Structure of AgCl
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• X-Ray K_β Emission and K Absorption Spectra of Chlorine in Sodium Chloride
• Sulfur-$K\beta$ X-Ray Emission Spectra of Alkaline-Earth Sulfides

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