Lα X-Ray Emission Spectra of Copper Compounds and Alloys
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概要
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With a two-crystal vacuum spectrometer equipped with beryl crystals, the Cu Lα emission spectra in fluorescence have been measured for selected copper compounds Cu_2O, CuO, CuCl, CuBr, CuI, CuF_2, CuCl_2, CuBr_2, CuF_2・2H_2O, CuCl_2・2H_2O and Cu_3P, and alloys α-Cu+35%Zn and Cu+2%Be. The measured spectra are grouped into three classes. The first class comprises the spectra of alloys, which consist of a single broad band similar to that of Cu metal. The second class includes the spectra of monovalent copper compounds, which are composed of a prominent peak and its high- and low-energy structures. To the third class belong the spectra of divalent copper compounds, which consist of a strong peak accompanied with a characteristic dip and hump on the high-energy side. The Cu Lα emission bands of Cu_2O, CuCl and CuBr are compared with available XPS spectra and theoretical Cu-3d-DOS.
- 社団法人日本物理学会の論文
- 1994-05-15
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