X-Ray Spectra and Electronic Structures of Rh and (NH_4)_3RhCl_6
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概要
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With a two-crystal vacuum spectrometer, the Rh Lβ_<2, 15> emission spectrum in fluorescence from (NH_4)_3 RhCl_6 has been measured together with that from rhodium metal. The metal spectrum consists of a single broad band, while the (NH_4)_3RhCl_6 spectrum is composed of a prominent peak and its low-energy shoulder. The measured Lβ_<2, 15> emission spectrum of Rh metal is compared with available X-ray photo-electron valence-band spectra and theoretical X-ray Lβ_<2, 15> emission spectra. It is shown that there is good agreement between them. The Rh Lβ_<2, 15> emission spectrum of (NH_4)_3RhCl_6 is presented along with the Rh L_<III> absorption, Cl Kβ emission and Cl K absorption spectra of this compound, reported previously. These spectra are interpreted in terms of the molecular orbitals of octahedral complex [RhCl_6]^<3->.
- 社団法人日本物理学会の論文
- 1993-07-15
著者
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Sugiura Chikara
Department Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University
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Sugiura Chikara
Department Of Applied Physics Faculty Of Engineering
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