Kα X-Ray Emission Spectra and K X-Ray Absorption-Edge Structures of Fluorine in 3d Transition-Metal Difluorides

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概要

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• The fluorine Kcx emission spectra in fluorescence from a series of 3d transition-metal difluorides MF. (M=Mn, Fe, Co, Ni, Cu and Zn) have been measured with ahigh-resolution two-crystal vacuum spectrometer. It is shown that the observedFWIIM of the Kcz... emission band is closely related to the difference in the elec-tronegativity between the metal and fluorine atoms. The measured emission spectraare presented along with the UPS or XPS spectra of the valence bands and thefluorine K absorption spectra of the metal difluorides, reported previously. The struc-lures at the fluorine K absorption edges are interpreted in terms of a molecular orbital(MO) model.3d transition-metal difluorides, X-ray emission spectra, X-ray absorption spec-tra, X-ray satellites, UPS spectra, XPS spectra, valence band, molecular orbital(MO), crystal-field splitting, electronegativity

• 社団法人日本物理学会の論文
• 1991-08-15

著者

• Sugiura Chikara

  Department Of Applied Physics Faculty Of Engineering

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