Electron Spin Resonance of Cr-^<3+> Ions Coupled with Oxygen Vacancies in Rutile
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概要
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Paramagnetic resonance of Cr^<3+> spins in TiO_2 single crystals were investigated in detail and two sets of weak absorption singnals were observed in addition to usual Cr^<3+> resonance lines. By analysing both the directions of the local symmetry axes and the magnitude of spin Hamiltonian parameters D and E of these two group I and II, it is concluded that these resonances come from substitutional Cr^<3+> spins coupled with the second and the third neighbor oxygen vacancies respectively. Spin Hamiltonian parameters determined for each group are given by Group I, g=1.98±0.005, D=5.10±0.10 GHz, E=-1.41±0.05 GHz Group II, g=1.98±0.005, D=-16.5±1.0 GHz, E=-3.9±0.5 GHz.
- 社団法人日本物理学会の論文
- 1969-01-05
著者
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Miyako Yoshihito
Department Of Earth And Space Science Faculty Of Science Osaka University
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Date Muneyuki
Department Of Physics Faculity Of Science Osaka University
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Ikebe Manabu
Department Of Materials Science And Technology Faculty Of Engineering Iwate University
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Ikebe Manabu
Department Of Physics Faculty Of Science Osaka University
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Miyako Yoshihito
Department Of Physics Faculty Of Science Osaka University:(present Address) Department Of Physics Fa
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