Structural Elucidation of 4-(Cystein-S-yl)butyl Glucosinolate from the Leaves of Eruca sativa
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概要
- 論文の詳細を見る
The structurally unique glucosinolate (GSL), 4-(cystein-S-yl)butyl GSL, was identified in the leaves of hydroponically-grown rocket salad (Eruca sativa Mill.). Its electrospray ionization mass spectrometry (ESI-MS)/MS spectrum indicated that this unusual GSL had a molecular weight of 414 as a desulfo (DS)-GSL, and a molecular formula of C14H25N2O8S2 based on its negative ion matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS) spectrum. For further confirmation, the 4-(cystein-S-yl)butyl DS-GSL was prepared with authentic L-Ser and purified dimeric 4-mercaptobutyl DS-GSL, and its chemical structure then confirmed by ESI-MS/MS data. It is named “glucorucolamine” as a trivial name from its ammonia sensitivity. This unique GSL was found to the greatest extent when rocket salad was grown in a 100% NH4+-N nutrient solution. Despite it clearly seems to reduce the detoxification of excess NH4+ in the leaves of rocket salad, present knowledge about the unique GSL is still far from being sufficient.
- 社団法人 日本農芸化学会の論文
- 2007-01-23
著者
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橋本 誠
北海道大学大学院農学研究院
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Kim Sun-ju
Memuro Upland Farming Research Station National Agricultural Research Center For Hokkaido Region
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Kim Sun-Ju
National Agricultural Research Center for Hokkaido Region
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Kawaharada Chiami
Obihiro University of Agriculture and Veterinary Medicine
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Jin Shigeki
Creative Research Initiative “Sousei,” Hokkaido University
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HASHIMOTO Makoto
Obihiro University of Agriculture and Veterinary Medicine
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ISHII Gensho
National Agricultural Research Center for Hokkaido Region
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YAMAUCHI Hiroaki
National Agricultural Research Center for Hokkaido Region
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JIN Shigeki
National Agricultural Research Center for Hokkaido Region
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Kim S‐j
Chiba Univ. Chiba Jpn
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Jin Shigeki
Hokkaido National Agricultural Experiment Station
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Kim Sun-ju
Graduate School Of Science And Technology Chiba University
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Yada H
National Agriculture Res. Center For Hokkaido Region
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Kim Sun-ju
Department Of Upland Agriculture National Agricultural Research Center For Hokkaido Region (narch)
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Yamauchi H
Department Of Upland Agriculture National Agricultural Research Center For Hokkaido Region
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Hashimoto Makoto
Obihiro Univ. Agriculture And Veterinary Medicine Hokkaido Jpn
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Jin Shigeki
Creative Research Initiative "sousei " Hokkaido University
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Hashimoto Makoto
Div. Of Applied Sci. Graduate School Of Agriculture Hokkaido Univ.
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Hashimoto Makoto
Department Of Agricultural And Life Science Obihiro University Of Agriculture And Veterinary Medicin
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Hashimoto Makoto
Department Of Agricultural And Life Science Obihiro University Of Agriculture And Veterinary Medicin
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Hashimoto Makoto
Department Of Bioresource Science Obihiro University Agriculture
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Hashimoto Makoto
Department Of Biology And Biochemistry University Of Bath:department Of Bioresource Science Obihiro
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Hashimoto Makoto
Department Of Agricultural And Life Science Obihiro University Of Agriculture And Veterinary Medicin
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Kim Sun‐ju
Memuro Upland Farming Research Station National Agricultural Research Center For Hokkaido Region
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